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Quality Level
Assay
97%
refractive index
n20/D 1.565 (lit.)
bp
124-125 °C/20 mmHg (lit.)
mp
15.5 °C (lit.)
density
1.392 g/mL at 25 °C (lit.)
SMILES string
COc1ccc(C)cc1Br
InChI
1S/C8H9BrO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,1-2H3
InChI key
DHPUIKWBNXTXOB-UHFFFAOYSA-N
Related Categories
General description
2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).
Application
2-Bromo-4-methylanisole may be used in the synthesis of:
- 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
- 1,8-dimethoxy-4-methylanthra-quinone
- ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
235.4 °F
Flash Point(C)
113 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Unambiguous synthesis and spectral characterization of 1,8-dihydroxy-4-methylanthraquinone.
ARKIVOC (Gainesville, FL, United States), 1, 80-84 (2002)
Poly (4-vinylpyridinium bromochromate): an efficient reagent for bromination of aromatic compounds.
Monatshefte fur Chemie / Chemical Monthly, 144(2), 179-181 (2013)
Highly efficient white organic electroluminescence from a double-layer device based on a boron hydroxyphenylpyridine complex.
Angewandte Chemie (International Edition in English), 41(1), 182-184 (2002)
Total synthesis of (?)-herbertenolide by stereospecific formation of vicinal quaternary centers in a crystalline ketone.
Organic Letters, 6(4), 645-647 (2004)
Lipase-Promoted Access to Phenolic Herbertane-Type Sesquiterpenes: (+)-1, 14-Herbertenediol, (-)-a-Herbertenol, (-)-Herbertenediol and Their Enantiomers.
European Journal of Organic Chemistry, 2004(24), 5092-5099 (2004)
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