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Safety Information

479896

Sigma-Aldrich

Luperox® 231, 1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane

92%

Synonym(s):

1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane

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About This Item

Linear Formula:
[(CH3)3COO]2C6H7(CH3)3
CAS Number:
6731-36-8
Molecular Weight:
302.45
EC Number:
229-782-3
MDL number:
MFCD00084801
UNSPSC Code:
12162002
PubChem Substance ID:
24871659

Quality Level

100

Assay

92%

refractive index

n20/D 1.441 (lit.)

mp

≥50 °C (SADT) (lit.)

density

0.904 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC1CC(C)(C)CC(C1)(OOC(C)(C)C)OOC(C)(C)C

InChI

1S/C17H34O4/c1-13-10-16(8,9)12-17(11-13,20-18-14(2,3)4)21-19-15(5,6)7/h13H,10-12H2,1-9H3

InChI key

NALFRYPTRXKZPN-UHFFFAOYSA-N

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Application

Polymerization Initiator

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Pictograms

Exploding BombFlame
GHS01,GHS02

Signal Word

Danger

Hazard Statements

H241,H413

Hazard Classifications

Aquatic Chronic 4 - Org. Perox. B

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX1372
MKCT0824
MKCP0167
MKCS6688
MKCQ9320

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Xiaopeng Shan et al.
Proceedings of the National Academy of Sciences of the United States of America, 102(15), 5340-5345 (2005-04-02)
The reaction of [Fe(2)(mu-OH)(2)(6-Me(3)-TPA)(2)](2+) (1) [6-Me(3)-TPA, Tris(6-methyl-2-pyridylmethyl)amine] with O(2) in CH(2)Cl(2) at -80 degrees C gives rise to two new intermediates, 2 and 3, before the formation of previously characterized [Fe(2)(O)(O(2))(6-Me(3)-TPA)(2)](2+) (4) that allow the oxygenation reaction to be monitored
M Mitsui et al.
Eisei Shikenjo hokoku. Bulletin of National Institute of Hygienic Sciences, (110)(110), 42-48 (1992-01-01)
A 13-week subchronic toxicity study of 1,1-bis(t-butylperoxy)3,3,5-trimethyl cyclohexane (TMCH) was performed in male and female B6C3F1 mice by feeding a CRF-1 powder diet containing 0, 0.5, 1.0, 2.0 and 4.0% TMCH, to determine the maximum tolerable dose (MTD) for subsequent
V S Trubetskoy et al.
Bioconjugate chemistry, 10(4), 624-628 (1999-07-20)
The assembly of DNA into compact particles that do not aggregate in physiologic salt solution occurs naturally in chromatin and viral particles but has been challenging to duplicate using artificial constructs. Cross-linking amino-containing polycations in the presence of DNA with
[Extraction-photometric analysis of low levels of hem-ditret-butylperoxy-3,3,5-trimethylcyclohexane peroxide in in water solutions].
E M Sevost'ianova et al.
Gigiena i sanitariia, (8)(8), 90-91 (1990-08-01)
Jo-Ming Tseng et al.
Journal of hazardous materials, 192(3), 1427-1436 (2011-07-26)
Over the past 30 years, the field of thermal analysis of organic peroxides has become an important issue in chemical engineering departments, safety departments, and in companies working with polymerization, petrifaction process, and so on. The contributions of thermal analysis
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