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(−)-O-Formyl-D-mandeloyl chloride, (R)-(−)-α-(Formyloxy)phenylacetyl chloride
HCO2CH(C6H5)COCl
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Quality Level
Assay
97%
optical activity
[α]23/D −228°, neat
refractive index
n20/D 1.523 (lit.)
bp
221 °C (lit.)
density
1.275 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClC(=O)[C@H](OC=O)c1ccccc1
InChI
1S/C9H7ClO3/c10-9(12)8(13-6-11)7-4-2-1-3-5-7/h1-6,8H/t8-/m1/s1
InChI key
ZNLABNPTWSKGDX-MRVPVSSYSA-N
Related Categories
Application
(R)-(−)-O-Formylmandeloyl chloride can be used as a chiral resolving agent for the resolution of spirobiindane.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
235.4 °F
Flash Point(C)
113 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Synthesis and application of a new hexamethyl-1, 1′-spirobiindane-based chiral bisphosphine (HMSI-PHOS) ligand in asymmetric allylic alkylation
Organic & Biomolecular Chemistry, 16(13), 2239-2247 (2018)
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