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474800

Sigma-Aldrich

tert-Butyl N,N-diallylcarbamate

98%

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Linear Formula:
(H2C=CHCH2)2NCO2C(CH3)3
CAS Number:
Molecular Weight:
197.27
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

refractive index

n20/D 1.442 (lit.)

bp

75 °C/1.5 mmHg (lit.)

density

0.914 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)OC(=O)N(CC=C)CC=C

InChI

1S/C11H19NO2/c1-6-8-12(9-7-2)10(13)14-11(3,4)5/h6-7H,1-2,8-9H2,3-5H3

InChI key

RRIPHUBKNVVTBM-UHFFFAOYSA-N

General description

tert-Butyl N,N-diallylcarbamate is a protected amine. Ring-closing metathesis (RCM) reactions of tert-butyl N,N-diallylcarbamate in the presence of Hoveyda-Grubbs type catalyst supported on mesoporous molecular sieves have been reported.

Application

tert-Butyl N,N-diallylcarbamate may be used in the synthesis of heterocyclic compounds.

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Regulatory Information

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Hynek Balcar et al.
Beilstein journal of organic chemistry, 7, 22-28 (2011-02-03)
A commercially available Hoveyda-Grubbs type catalyst (RC303 Zhannan Pharma) was immobilized on mesoporous molecular sieves MCM-41 and on SBA-15 by direct interaction with the sieve wall surface. The immobilized catalysts exhibited high activity and nearly 100% selectivity in several types
Copper-Catalyzed Synthesis of 1, 2-Disubstituted Cyclopentanes from 1, 6-Dienes by Ring-Closing Kharasch Addition of Carbon Tetrachloride.
Mu?oz-Molina JM, et al.
Advanced Synthesis & Catalysis, 350(14-15), 2365-2372 (2008)

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