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474428

Sigma-Aldrich

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate

95%

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Synonym(s):
DFHA
Linear Formula:
H2C=CHCO2CH2(CF2)5CHF2
CAS Number:
2993-85-3
Molecular Weight:
386.13
EC Number:
221-064-8
MDL number:
MFCD00080746
UNSPSC Code:
12162002
PubChem Substance ID:
24871004
NACRES:
NA.23

Quality Level

100

Assay

95%

contains

100 ppm 4-tert-butylcatechol as inhibitor

refractive index

n20/D 1.342 (lit.)

bp

197 °C (lit.)

density

1.581 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C

InChI

1S/C10H6F12O2/c1-2-4(23)24-3-6(13,14)8(17,18)10(21,22)9(19,20)7(15,16)5(11)12/h2,5H,1,3H2

InChI key

QJEJDNMGOWJONG-UHFFFAOYSA-N

Related Categories

General description

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate (DFHA) is a fluorous functional monomer that is majorly used in the surface functionalization. It can also be utilized in chemical vapor deposition process for the synthesis of nanomaterials.

Application

DFHA can be used in the preparation of hybrid fluorous monolithic columns for nano-liquid chromatography. It can be used in the surface modification of multi-walled carbon nanotubes (MWCNTs) for the formation of highly conductive composites.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

215.6 °F

Flash Point(C)

102 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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One-pot two-step perfluoroalkylsilane functionalization of multi-walled carbon nanotubes for polyurethane-based composites
Li S, et al.
Composites Science and Technology, 143, 46-55 (2017)
Vapor-deposited fluorinated glycidyl copolymer thin films with low surface energy and improved mechanical properties
Mao Y and Gleason KK
Macromolecules, 39(11), 3895-3900 (2006)
Haiyang Zhang et al.
Journal of chromatography. A, 1440, 66-73 (2016-02-27)
A hybrid fluorous monolithic column was simply prepared via photo-initiated free radical polymerization of an acrylopropyl polyhedral oligomeric silsesquioxane (acryl-POSS) and a perfluorous monomer (2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate) in UV-transparent fused-silica capillaries within 5min. The physical characterization of hybrid fluorous monolith, including

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