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Sigma-Aldrich

2-Bromophenylboronic acid

greener alternative

≥95.0%

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Synonym(s):
o-Bromophenylboronic acid
Linear Formula:
BrC6H4B(OH)2
CAS Number:
244205-40-1
Molecular Weight:
200.83
MDL number:
MFCD01114672
UNSPSC Code:
12352103
PubChem Substance ID:
24870934
NACRES:
NA.22

Quality Level

200

Assay

≥95.0%

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

113 °C (lit.)

greener alternative category

Aligned,

SMILES string

OB(O)c1ccccc1Br

InChI

1S/C6H6BBrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H

InChI key

PLVCYMZAEQRYHJ-UHFFFAOYSA-N

Related Categories

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Other Notes

Contains varying amounts of anhydride

related product

Product No.
Description
Pricing

901627

Pym-DATB Catalyst

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Certificates of Analysis (COA)

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Yae In Cho et al.
Inorganic chemistry, 58(19), 12689-12699 (2019-09-10)
We report syntheses and H2 activation involving model complexes of mono-iron hydrogenase (Hmd) derived from acyl-containing pincer ligand precursors bearing thioether (CNS

Articles

Greener Methods: Catalytic Amide Bond Formation

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