473235
N,N-Diethylhydroxylamine solution
85 wt. % in H2O
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Synonym(s):
N-Hydroxydiethylamine, DEHA, Diethylhydroxylamine
Linear Formula:
(C2H5)2NOH
CAS Number:
Molecular Weight:
89.14
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
concentration
85 wt. % in H2O
refractive index
n20/D 1.419
bp
125-130 °C
mp
−25 °C
density
0.902 g/mL at 25 °C
SMILES string
CCN(O)CC
InChI
1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3
InChI key
FVCOIAYSJZGECG-UHFFFAOYSA-N
General description
The product is 85wt.% solution of N,N-diethylhydroxylamine. The reaction of N,N-diethylhydroxylamine with tert-butylhydroperoxide has been studied. It participates in the preparation of symmetrical and an isomeric mixture of unsymmetrical phthalocyanines. It undergoes degradation on exposure to radiation and affords light hydrocarbons. Qualitative and quantitative analyses of the produced hydrocarbons have been reported. It also participates in the conversion of quinones and quinonemonosulfonimide to the corresponding hydroquinones and sulfonylaminophenols, respectively.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
WGK
WGK 1
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Certificates of Analysis (COA)
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Novel and Mild Route to Phthalocyanines and 3-Iminoisoindolin-1-ones via N, N-Diethylhydroxylamine-Promoted Conversion of Phthalonitriles and a Dramatic Solvent-Dependence of the Reaction.
Luzyanin KV, et al.
Advanced Synthesis & Catalysis, 350(1), 135-142 (2008)
Oxidation of N, N-dialkyl hydroxylamines with t-butyl hydroperoxide. A new synthesis for nitrones.
Mare HDL and Coppinger GM.
The Journal of Organic Chemistry, 28(4), 1068-1070 (1963)
Reduction of quinones and quinonemonosulfonimides with N, N-diethylhydroxylamine.
Fujita S and Sano K.
The Journal of Organic Chemistry, 44(15), 2647-2651 (1979)
Qualitative and quantitative analysis of the light hydrocarbons produced by radiation degradation of N, N-diethylhydroxylamine.
Wang J, et al.
J. Radioanal. Nucl. Chem., 262(2), 451-453 (2004)
Chronic inhalation study of mice subjected to diethylhydroxylamine, nitroethane, and diethylamine hydrogen sulfite.
J Heicklen et al.
Environmental research, 27(2), 277-289 (1982-04-01)
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