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470554

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

97%

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Synonym(s):
Ni(dppf)Cl2
Empirical Formula (Hill Notation):
C34H28Cl2FeNiP2
CAS Number:
67292-34-6
Molecular Weight:
683.98
MDL number:
MFCD00270284
UNSPSC Code:
12352300
PubChem Substance ID:
24870665
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: nickel
reagent type: catalyst

mp

285 °C (dec.) (lit.)

SMILES string

[Fe].Cl[Ni]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

NSSWUOVWGSDARH-UHFFFAOYSA-L

Related Categories

Pictograms

Health hazard
GHS08

Signal Word

Danger

Hazard Statements

H317,H334,H350

Hazard Classifications

Carc. 1B - Resp. Sens. 1 - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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