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Safety Information

469033

Sigma-Aldrich

Pentylmagnesium chloride solution

2.0 M in THF

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About This Item

Linear Formula:
CH3(CH2)4MgCl
CAS Number:
Molecular Weight:
130.90
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in THF

bp

65 °C

density

0.967 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCC[Mg]Cl

InChI

1S/C5H11.ClH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1

InChI key

OHLJPYMGJFINNA-UHFFFAOYSA-M

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.0 °F - closed cup

Flash Point(C)

-17.2 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method

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