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467634

Sigma-Aldrich

Barium titanate(IV)

nanopowder (cubic crystalline phase), <100 nm particle size (BET), ≥99% trace metals basis

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Synonym(s):
Titanium barium oxide
Linear Formula:
BaTiO3
CAS Number:
12047-27-7
Molecular Weight:
233.19
EC Number:
234-975-0
MDL number:
MFCD00003447
UNSPSC Code:
12352302
PubChem Substance ID:
24870427
NACRES:
NA.23

Quality Level

100

Assay

≥99% trace metals basis

form

nanopowder (cubic crystalline phase)

dielectric constant

150

reaction suitability

reagent type: catalyst
core: titanium

particle size

<100 nm (BET)

density

6.08 g/mL at 25 °C (lit.)

SMILES string

[Ba++].[O-][Ti]([O-])=O

InChI

1S/Ba.3O.Ti/q+2;;2*-1;

InChI key

WNKMTAQXMLAYHX-UHFFFAOYSA-N

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General description

Barium titanate(IV) is a ceramic material that can be synthesized by reacting titanium oxide (TiO2) and barium salts in the presence of oleic acid as a stabilizing agent. It has a cubic crystal structure which allows it to have ferroelectric, thermoelectric and piezoelectric properties. It forms a film with intense photoluminescence which can be used for a wide range of electronic applications.

Application

BaTiO3 can be used in the fabrication of flexible electronic devices with improved dielectric strength.

Physical form

Some agglomeration of nanoparticles may occur during the drying process, yielding particle sizes of up to 75 microns. These agglomerates can be broken up through ultrasonication, ball milling, or dispersion in solution with a surfactant.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H332

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

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    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

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    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What is the band gap energy and the electron affinity for Product 467634, Barium titanate?

    The band gap energy is 3.2 eV and the electron affinity is 4.15 eV for barium titanate. However, these properties are not measured for Product 467634, Barium titanate (IV).

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High-k dielectric composites of poly (2-cyanoethyl vinyl ether) and barium titanate for flexible electronics
Piana F, et al.
Journal of Applied Polymer Science, 134(37), 45236-45236 (2017)
A general soft-chemistry route to perovskites and related materials: synthesis of BaTiO3, BaZrO3, and LiNbO3 nanoparticles
Niederberger M, et al.
Angewandte Chemie (International Edition in English), 43(17), 2270-2273 (2004)
All-inkjet-printed electrical components and circuit fabrication on a plastic substrate
Kang BJ, et al.
Microelectronic Engineering, 97(16), 251-254 (2012)
Hydrothermal microwave: a new route to obtain photoluminescent crystalline BaTiO3 nanoparticles
Moreira ML, et al.
Chemistry of Materials, 20(16), 5381-5387 (2008)
Synthesis, Properties, and Applications of Perovskite Phase Metal Oxide Nanostructures
Mao Y, et al.
Material Matters, 5(2), 50-50 (2010)
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