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Merck
CN

466352

Tin(II) iodide

−10 mesh, 99.999% trace metals basis

Synonym(s):

Stannous iodide, Tin diiodide

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About This Item

Linear Formula:
SnI2
CAS Number:
10294-70-9
Molecular Weight:
372.52
NACRES:
NA.23
PubChem Substance ID:
24870342
UNSPSC Code:
12352302
EC Number:
233-667-3
MDL number:
MFCD00049545
Assay:
99.999% trace metals basis
Form:
powder

Key Documents

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Product Name

Tin(II) iodide, −10 mesh, 99.999% trace metals basis

InChI key

JTDNNCYXCFHBGG-UHFFFAOYSA-L

InChI

1S/2HI.Sn/h2*1H;/q;;+2/p-2

SMILES string

I[SnH2]I

assay

99.999% trace metals basis

form

powder

reaction suitability

core: tin

impurities

≤15.0 ppm Trace Metal Analysis

bp

714 °C (lit.)

mp

320 °C (lit.)

density

5.28 g/mL at 25 °C (lit.)

application(s)

material synthesis precursor
perovskite solar cells

Quality Level

100

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Application

Tin(II) iodide can be used:
  • As a precursor to fabricate methylammonium tin iodide films for heterojunction-depleted perovskite solar cells using solvent-mediated crystallization.
  • To prepare highly stable perovskite thin films for Pb-free light-emitting diodes(PeLEDs). and a new air-stable one-dimensional (1D) hybrid lead-free halide material (DAO)Sn2I6 which emits broad orange light at 634 nm and photoluminescence quantum yield of 36%.
  • As a dual-functional electrolyte additive in high-rate Li-air batteries. SnI2 protects the lithium anode and reduces charge potential by promoting the decomposition of the Li2O2.
  • To synthesize mixed Pb–Sn perovskite films with formamidine sulfinic acid(FSA) for all tandem perovskite solar cells.

General description

Tin(II) iodide is an orange crystalline solid with a high melting point. It is widely used to fabricate organic–inorganic solar cells, light-emitting devices, and secondary batteries. It acts as a reducing agent.

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3

target_organs

Cardio-vascular system,hematopoietic system, Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000457033
0000457033
0000399059
0000369964
0000369964

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Enhancing performance and stability of tin halide perovskite light emitting diodes via coordination engineering of lewis acid--base adducts
Ye Jin Heo, et al.
Advanced Functional Materials , 31, 210697-210697 (2021)
Solvent-mediated crystallization of CH3NH3SnI3 films for heterojunction depleted perovskite solar cells
Feng Hao, et al.
Journal of the American Chemical Society, 137, 11445-11452 (2015)
Water-stable 1D hybrid tin (II) iodide emits broad light with 36\% photoluminescence quantum efficiency
Ioannis Spanopoulos, et al.
Journal of the American Chemical Society, 142, 9028-9038 (2020)
All-perovskite tandem solar cells with 24.2\% certified efficiency and area over 1 cm2 using surface-anchoring zwitterionic antioxidant
Ke Xiao, et al.
Nature Energy, 5, 870-880 (2020)
Novel Co-Catalytic Activities of Solid and Liquid Phase Catalysts in High-Rate Li-Air Batteries
Chengji Zhang, et al.
Advanced Energy Materials, 12, 2201616-2201616 (2022)
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