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466212

Sigma-Aldrich

1,1,2-Trichloroethane

contains ≤3% 2-propanol as stabilizer, 97%

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Synonym(s):
β-Trichloroethane, Vinyltrichloride
Linear Formula:
ClCH2CHCl2
CAS Number:
79-00-5
Molecular Weight:
133.40
Beilstein:
1731726
MDL number:
MFCD00000852
UNSPSC Code:
12352100
PubChem Substance ID:
24870333
NACRES:
NA.22

Assay

97%

contains

≤3% 2-propanol as stabilizer

refractive index

n20/D 1.471 (lit.)

bp

110-115 °C (lit.)

density

1.435 g/mL at 25 °C (lit.)

SMILES string

ClCC(Cl)Cl

InChI

1S/C2H3Cl3/c3-1-2(4)5/h2H,1H2

InChI key

UBOXGVDOUJQMTN-UHFFFAOYSA-N

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General description

1,1,2-Trichloroethane (1,1,2-TCA), a chlorinated aliphatic hydrocarbon, is a common groundwater pollutant. Microbial detoxification of 1,1,2-TCA has been studied. Ni supported on mesoporous silica (SBA-16) catalyzed hydrodechlorination of 1,1,2-trichloroethane has been reported. Rotational isomers of 1,1,2-trichloroethane in the gaseous and liquid states have been investigated by the infrared absorption spectra.

Application

  • Advanced Material Development: Research into the synthesis of UiO-66 3D photonic crystals highlights the use of 1,1,2-Trichloroethane in the creation of new materials for efficient vapor detection, supporting advancements in sensor technology (Wang et al., 2022).

Pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2

Supplementary Hazards

EUH066

WGK

WGK 3

Regulatory Information

危险化学品

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Siyan Zhao et al.
PloS one, 10(3), e0119507-e0119507 (2015-04-04)
1,1,2-trichloroethane (1,1,2-TCA) has become a common groundwater pollutant due to historically extensive utilization, improper disposal, as well as from incomplete dechlorination of 1,1,2,2-tetrachloroethane. Currently, limited information is available on microbial detoxification of 1,1,2-TCA. Desulfitobacterium sp. strain PR, which was isolated
Infrared Absorption Investigation on the Rotational Isomerism of 1, 1, 2-Trichloroethane.
Kuratani K and Mizushima S-I.
J. Chem. Phys. , 22(8), 1403-1405 (1954)
Single-step preparation of Ni catalysts supported on mesoporous silicas (SBA-15 and SBA-16) and the effect of pore structure on the selective hydrodechlorination of 1, 1, 2-trichloroethane to VCM.
Park Y, et al.
Catalysis Today, 97(2), 195-203 (2004)
Kenneth Y Lee et al.
Journal of hazardous materials, 128(2-3), 218-226 (2005-10-06)
This paper presents the results from a well-defined, circular-shaped, multicomponent dense nonaqueous phase liquid (DNAPL) pool dissolution experiment conducted in a three-dimensional, bench scale model aquifer. The multicomponent pool is a mixture of tetrachloroethylene (PCE) and 1,1,2-trichloroethane (1,1,2-TCA); PCE was
Ariel Grostern et al.
Applied and environmental microbiology, 72(1), 428-436 (2006-01-05)
Mixed anaerobic microbial subcultures enriched from a multilayered aquifer at a former chlorinated solvent disposal facility in West Louisiana were examined to determine the organism(s) involved in the dechlorination of the toxic compounds 1,2-dichloroethane (1,2-DCA) and 1,1,2-trichloroethane (1,1,2-TCA) to ethene.
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