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About This Item
Linear Formula:
(CH3)2Si(Cl)OSi(Cl)(CH3)2
CAS Number:
Molecular Weight:
203.21
Beilstein:
1741218
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
refractive index
n20/D 1.407 (lit.)
bp
138 °C (lit.)
density
1.039 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(Cl)O[Si](C)(C)Cl
InChI
1S/C4H12Cl2OSi2/c1-8(2,5)7-9(3,4)6/h1-4H3
InChI key
DMEXFOUCEOWRGD-UHFFFAOYSA-N
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Application
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane can be used to prepare:
- A Silicon-based fluorene polymer by reacting with a dibromofluorene derived Grignard reagent.
- ansa-Metallocene compound i.e, ansa-[TiCl2{η5:η5-(C5H4SiMe2)2O}].
- Silaanthracenophanes.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
59.0 °F - closed cup
Flash Point(C)
15 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Synthesis and Structures of New Silaanthracenophanes
Lee I, et al.
Bulletin of the Korean Chemical Society,, 33(1), 255-260 (2012)
Synthesis and crystal structures of μ-1, 3-bis (η5-tetramethylcyclopentadienyl)-1, 1, 3, 3-tetramethyldisiloxane)[ η2-bis (trimethylsilyl) ethyne] titanium (II) and a doubly tucked-in product of its thermolysis
Horacek M, et al.
Journal of Organometallic Chemistry, 658(1-2), 235-241 (2002)
Carbon-Silicon coupling between fluorenyl Grignard reagents and dichlorosilanes for synthesis of novel copolymers and chemical properties of the copolymers
Kitamura N and Yamamoto T
Applied Organometallic Chemistry, 17(11), 840-842 (2003)
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