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Merck
CN

463353

tert-Butyl methacrylate

98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor

Synonym(s):

1,1-Dimethylethyl methacrylate, tert -Butyl α-methacrylate, tert -Butyl methacrylate, Acryester TB

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About This Item

Linear Formula:
H2C=C(CH3)CO2C(CH3)3
CAS Number:
585-07-9
Molecular Weight:
142.20
NACRES:
NA.23
PubChem Substance ID:
24870053
UNSPSC Code:
12162002
EC Number:
209-548-7
MDL number:
MFCD00048245

Key Documents

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Product Name

tert-Butyl methacrylate, 98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor

InChI key

SJMYWORNLPSJQO-UHFFFAOYSA-N

InChI

1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3

SMILES string

CC(=C)C(=O)OC(C)(C)C

assay

98%

contains

200 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.415 (lit.)

bp

132 °C (lit.)

density

0.875 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

200

Related Categories

Application

tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

86.0 °F - closed cup

flash_point_c

30 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCW8654
MKCT6164
MKCQ6750
MKCS1585
MKCS7934

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Homo and block copolymers of tert-butyl methacrylate by atom transfer radical polymerization
Krishnan R and Srinivasan KSV
European Polymer Journal, 40(10), 2269-2276 (2004)
Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations
Buback M and Junkers T
Macromolecular Chemistry and Physics, 207(18), 1640-1650 (2006)
Phase behavior of linear polystyrene-block-poly (2-vinylpyridine)-block-poly (tert-butyl methacrylate) triblock terpolymers
Ludwigs S, et al.
Polymer, 44(22), 6815-6823 (2003)
Hironori Kumagai et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 136, 29-37 (2019-01-15)
We are investigating an imaging agent for early detection of colorectal cancer. The agent, named the nanobeacon, is coumarin 6-encapsulated polystyrene nanospheres whose surfaces are covered with poly(N-vinylacetamide) and peanut agglutinin that reduces non-specific interactions with the normal mucosa and
Yue Liu et al.
Colloids and surfaces. B, Biointerfaces, 136, 721-728 (2015-10-30)
A novel nanoparticle with multilayer core-shell architecture for cell imaging is designed and synthesized by coating a fluorescent YVO4:Eu core with a diblock copolymer, MPEG-b-PMAA. The synthesis of YVO4:Eu core, which further makes MPEG-b-PMAA-YVO4:Eu NPs adapt for cell imaging, is
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