All Photos(1)
Synonym(s):
2-Benzylaminoethylamine
Linear Formula:
C6H5CH2NHCH2CH2NH2
CAS Number:
Molecular Weight:
150.22
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
97%
refractive index
n20/D 1.54 (lit.)
bp
162 °C/20 mmHg (lit.)
density
1 g/mL at 25 °C (lit.)
SMILES string
NCCNCc1ccccc1
InChI
1S/C9H14N2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5,11H,6-8,10H2
InChI key
ACYBVNYNIZTUIL-UHFFFAOYSA-N
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General description
N-Benzylethylenediamine participates in the one-pot synthesis of N,N,N′-trisubstituted guanidines. It undergoes condensation with dibenzoylmethane (1,3-diphenyl-1,3-propanedione) in stoichiometric ratio 1:1 to afford the corresponding Schiff monobase.
Application
N-Benzylethylenediamine may be used for the synthesis of N-benzyl-N,N′,N′-tris(tert-butyloxycarbonylmethyl)ethylenediamine and 3-benzyl-2-(phenyl-2-sulfonate)-2-imidazoline tetraheptylammonium salt.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Certificates of Analysis (COA)
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Nickel (II) Complexes of Dibenzoylmethane and N-benzylethylenediamine, and Their Schiff Monobase.
Gutierrez JA, et al.
Journal of Coordination Chemistry, 28(3-4), 305-312 (1993)
Application of a-chloroaldoxime O-methanesulfonates to one-pot synthesis of N, N', N?-substituted guanidines via Tiemann rearrangement.
Yamamoto Y, et al.
Tetrahedron Letters, 50(42), 5813-5815 (2009)
A new method for the synthesis of tri-tert-butyl diethylenetriaminepentaacetic acid and its derivatives.
Achilefu S, et al.
The Journal of Organic Chemistry, 65(5), 1562-1565 (2000)
Anthony Weatherwax et al.
Organic letters, 7(16), 3461-3463 (2005-07-29)
Trans-disubstituted beta-lactams show increasing utility and prominence in numerous pharmaceutical applications, making their asymmetric synthesis an attractive goal for chemists. We introduce an anionic, nucleophilic catalyst system that provides an efficient, diastereoselective route to trans-disubstituted beta-lactams, a complement to our
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