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459097

Sigma-Aldrich

Copper(II) chloride dihydrate

99.999%

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Synonym(s):
Cupric chloride dihydrate
Linear Formula:
CuCl2 · 2H2O
CAS Number:
10125-13-0
Molecular Weight:
170.48
EC Number:
231-210-2
MDL number:
MFCD00149674
UNSPSC Code:
12352302
PubChem Substance ID:
24869509
NACRES:
NA.23

vapor density

>1 (vs air)

Quality Level

100

Assay

99.999%

form

solid

impurities

≤15.0 ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Cu]Cl.[H]O[H].[H]O[H]

InChI

1S/2ClH.Cu.2H2O/h2*1H;;2*1H2/q;;+2;;/p-2

InChI key

MPTQRFCYZCXJFQ-UHFFFAOYSA-L

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Application

Copper chloride dehydrate refluxed in acetonitrile can chemoselectively hydrolyze semicarbazones to carbonyl compounds. Copper chloride dehydrate may be used as a catalyst for efficiently cleaving t-butyldimethylsilyl (TBDMS).

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

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Deprotection of t-butyldimethylsiloxy (TBDMS) protecting group with catalytic copper (II) chloride dihydrate.
Ping Z, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 11(19), 753-756 (2000)
Hellinida Thomadaki et al.
Journal of medicinal chemistry, 51(13), 3713-3719 (2008-06-06)
We studied the antitumor properties of the dinuclear copper(II) complex of l-carnitine [Cu 2( l-carnitine) 2Cl 2(H 2O) 2]Cl 2, as well as those of l-carnitine and copper chloride dihydrate, in human leukemic cells. The complex was synthesized and characterized
Sebastian Müller et al.
PloS one, 13(11), e0206764-e0206764 (2018-11-07)
The clinically approved drug metformin has been shown to selectively kill persister cancer cells through mechanisms that are not fully understood. To provide further mechanistic insights, we developed a drug surrogate that phenocopies metformin and can be labeled in situ
Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates.
Andrew T Parsons et al.
Angewandte Chemie (International ed. in English), 51(12), 2947-2950 (2012-02-14)
Bin Wu et al.
Carbohydrate research, 351, 68-73 (2012-03-01)
Two new glucoside esters 1 and 2 were produced as stress metabolites in the fresh leaves of Portulaca oleracea, in response to abiotic stress elicitation by CuCl(2). A new sugar ester (3) and two known compounds (4 and 5) were
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