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454664

2-Hydroxy-5-methylbenzaldehyde

Name: 2-Hydroxy-5-methylbenzaldehyde
Brand: ALDRICH

98%

Synonym(s):

5-Methylsalicylaldehyde, 2,5-Cresotaldehyde

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About This Item

Linear Formula:

HOC₆H₃(CH₃)CHO

CAS Number:

613-84-3

Molecular Weight:

136.15

Beilstein:

2040673

EC Number:

210-357-6

MDL number:

MFCD00274297

UNSPSC Code:

12352100

PubChem Substance ID:

24868951

NACRES:

NA.22

Assay

98%

form

solid

bp

217 °C (lit.)

mp

54-57 °C (lit.)

SMILES string

Cc1ccc(O)c(C=O)c1

InChI

1S/C8H8O2/c1-6-2-3-8(10)7(4-6)5-9/h2-5,10H,1H3

InChI key

ILEIUTCVWLYZOM-UHFFFAOYSA-N

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Related Categories

Aldehydes

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Organic Building Blocks

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Spectroscopy and stereochemistry of the optically active copper (II), cobalt (II) and nickel (II) complexes with Schiff bases N,N'-(1R,2R)-(-)-1, 2-cyclohexylenebis(3-methylbenzylideneiminato) and N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(5-methylbenzylideneiminato)

Szlyk E, et al.

Polyhedron, 21(27), 2711-2717 (2002)

Synthesis, Spectral Characterization, DNA/ Protein Binding, DNA Cleavage, Cytotoxicity, Antioxidative and Molecular Docking Studies of Cu(II)Complexes Containing Schiff Base-bpy/Phen Ligands.

Berelli Anupama et al.

Journal of fluorescence, 27(3), 953-965 (2017-01-18)

Ternary Cu(II) complexes [Cu(II)(L)(bpy)Cl] 1, [Cu(II)(L)(Phen)Cl] 2 [L = 2,3-dimethyl-1-phenyl-4(2 hydroxy-5-methyl benzylideneamino)-pyrazol-5-one, bpy = 2,2

Effect of Ligand Field Strength on the Spin Crossover Behaviour in 5-X-SalEen (X=Me, Br and OMe) Based Fe(III) Complexes.

Bijoy Dey et al.

Chemistry, an Asian journal, 15(11), 1709-1721 (2020-04-18)

The reaction of Fe(NCS)3 prepared in situ in MeOH with 5-X-SalEen ligands (5-X-SalEen=condensation product of 5-substituted salicylaldehyde and N-ethylethylenediamine) provided three Fe(III) complexes, [Fe(5-X-SalEen)2 ]NCS; X=Me (1), X=Br (2), X=OMe (3). All the complexes reveal similar structural features but a very

Short Radiative Lifetime and Non-Triplet Sensitization in Near-Infrared-Luminescent Yb(III) Complex with Tripodal Schiff Base.

Atsuko Masuya-Suzuki et al.

ChemistryOpen, 10(1), 46-55 (2021-01-22)

We prepared Ln(III) (Ln=Eu, Gd, and Yb) complexes with a tripodal Schiff base, tris[2-(5-methylsalicylideneimino)ethyl]amine (H3 L) and studied their photophysical properties. Upon ligand excitation, YbL showed Yb(III)-centered luminescence in the near-infrared region. While the overall quantum yield (0.60(1)%) of YbL

Syntheses, structures and electrochemistry of copper (II) salicylaldehyde/tris (3-phenylpyrazolyl) borate complexes as models for the radical copper oxidases.

Halcrow MA, et al.

J. Chem. Soc., Dalton Trans., 11, 1753-1762 (1999)

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