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451622

Sigma-Aldrich

Lithium tetrafluoroborate

greener alternative

ultra dry, powder, 99.99% trace metals basis

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Synonym(s):
Lithium borofluoride, Lithium fluoroborate
Linear Formula:
LiBF4
CAS Number:
14283-07-9
Molecular Weight:
93.75
EC Number:
238-178-9
MDL number:
MFCD00011087
UNSPSC Code:
12352302
PubChem Substance ID:
24868639
NACRES:
NA.23

description

Grade: ultra dry

Quality Level

200

Assay

99.99% trace metals basis

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤150.0 ppm Trace Metal Analysis

mp

293-300 °C (dec.) (lit.)

application(s)

battery manufacturing

greener alternative category

, Enabling

SMILES string

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

InChI key

UFXJWFBILHTTET-UHFFFAOYSA-N

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General description

Lithium tetrafluoroborate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiBF4 is majorly used as an electrolyte with good ionic conductivity. It facilitates the formation of an electrolytic solution or a liquid electrolyte, which can be used in the fabrication of lithium-ion batteries and solid-state electrochemical displays.
Used recently in the development of a solid composite electrolyte for lithium batteries.

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Signal Word

Danger

Hazard Statements

H302,H314,H341

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Zachary T Gossage et al.
The Analyst, 145(7), 2631-2638 (2020-02-27)
Interphases formed at battery electrodes are key to enabling energy dense charge storage by acting as protection layers and gatekeeping ion flux into and out of the electrodes. However, our current understanding of these structures and how to control their
Application of di-ureasil ormolytes based on lithium tetrafluoroborate in solid-state electrochromic displays
Barbosa P, et al.
Journal of Materials Chemistry, 20(4), 723-730 (2010)
A new lithium salt with dihydroxybenzene and lithium tetrafluoroborate for lithium battery electrolytes
Xue Z, et al.
Journal of Power Sources, 196(20), 8710-8713 (2011)
Proc. Power Sources Conf., 37th, 287-287 (1996)
Novel polymer electrolyte from poly (carbonate-ether) and lithium tetrafluoroborate for lithium-oxygen battery
Lu Q, et al.
Journal of Power Sources, 242, 677-682 (2013)
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