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Merck
CN

451142

Lithium tetrachloroaluminate

anhydrous, beads, −10 mesh, 99.99% trace metals basis

Synonym(s):

Aluminum lithium chloride (AlLiCl4 ), Lithium aluminum tetrachloride, Lithium tetrachloroaluminate (LiAlCl4 )

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About This Item

Linear Formula:
LiAlCl4
CAS Number:
14024-11-4
Molecular Weight:
175.73
UNSPSC Code:
12352302
PubChem Substance ID:
24868606
EC Number:
237-850-9
MDL number:
MFCD00061440

Key Documents

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InChI key

AQLRWYUVWAYZFO-UHFFFAOYSA-J

InChI

1S/Al.4ClH.Li/h;4*1H;/q+3;;;;;+1/p-4

SMILES string

[Li+].Cl[Al-](Cl)(Cl)Cl

grade

anhydrous

assay

99.99% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: aluminum

particle size

−10 mesh

Application

A high-energy, new battery system using only inorganic constituents has been designed where Li and LiCoO2 serve as the electrodes in a LiAlCl4-in-SO2 liquid electrolyte. Has been studied for cell performance characteristics and reaction products of LiAlCl4 and LiGaCl4 in a variety of battery systems.
Used in studies of electrochemical cell reactions.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW9710V
MKBS9640V
MKBN5043V
MKBJ3882V
MKBH6950V

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Hill, I.R. et al.
Journal of the Electrochemical Society, 142, 3267-3267 (1995)

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