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450219

Sigma-Aldrich

Silver hexafluorophosphate

99.99% trace metals basis

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Synonym(s):
Silver hexafluorophosphate (AgPF6 ), Silver(1+) hexafluorophosphate
Linear Formula:
AgPF6
CAS Number:
26042-63-7
Molecular Weight:
252.83
EC Number:
247-428-6
MDL number:
MFCD00003415
UNSPSC Code:
12352302
PubChem Substance ID:
24868543
NACRES:
NA.23

Quality Level

100

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: silver

impurities

≤150.0 ppm Trace Metal Analysis

mp

102 °C (dec.) (lit.)

SMILES string

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI key

SCQBROMTFBBDHF-UHFFFAOYSA-N

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Application

Used in the development of new catalyst systems for stereoselective addition of alcohols to alkynes. Acidic catalyst for the synthesis of unsymmetrical sulfides and vinyl fluorides. Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280 - P305 + P351 + P338 - P310

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Synthetic Communications, 22, 1461-1461 (1992)
Chemistry Letters (Jpn), 727-727 (1996)
Chemistry Letters (Jpn), 1-1 (1993)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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