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447145

Sigma-Aldrich

Borane dimethyl sulfide complex solution

5.0 M in diethyl ether

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Synonym(s):
BMS, Trihydro[thiobis[methane]]boron
Linear Formula:
(CH3)2S · BH3
CAS Number:
13292-87-0
Molecular Weight:
75.97
Beilstein:
3663489
MDL number:
MFCD00013189
UNSPSC Code:
12352112
PubChem Substance ID:
24868320
NACRES:
NA.22

reaction suitability

reagent type: reductant

concentration

5.0 M in diethyl ether

bp

~34 °C

density

0.789 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Application

Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019,EUH066

WGK

WGK 1

Flash Point(F)

-31.0 °F

Flash Point(C)

-35 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Amine modified electrospun PIM-1 ultrafine fibers for an efficient removal of methyl orange from an aqueous system
Satilmis B and Uyar T
Applied Surface Science, 453, 220-229 (2018)
Isidoro González-Álvaro et al.
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