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Merck
CN

446653

Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine

Dye content 80 %

Synonym(s):

F16CuPc

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About This Item

Empirical Formula (Hill Notation):
C32CuF16N8
CAS Number:
14916-87-1
Molecular Weight:
863.92
NACRES:
NA.23
PubChem Substance ID:
24868290
UNSPSC Code:
12352103
MDL number:
MFCD00274642

Key Documents

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Product Name

Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine, Dye content 80 %

Quality Level

100

λmax

689 nm

InChI

1S/C32F16N8.Cu/c33-9-1-2(10(34)18(42)17(9)41)26-49-25(1)53-27-3-4(12(36)20(44)19(43)11(3)35)29(50-27)55-31-7-8(16(40)24(48)23(47)15(7)39)32(52-31)56-30-6-5(28(51-30)54-26)13(37)21(45)22(46)14(6)38;/q-2;+2

SMILES string

Fc1c(F)c(F)c2c3nc(nc4n5[Cu]n6c(n3)c7c(F)c(F)c(F)c(F)c7c6nc8nc(nc5c9c(F)c(F)c(F)c(F)c49)c%10c(F)c(F)c(F)c(F)c8%10)c2c1F

InChI key

FJAOBQORBYMRNO-UHFFFAOYSA-N

form

powder

composition

Dye content, 80%

mp

>300 °C (lit.)

Related Categories

Application

F16CuPc can be used as an electron transporting layer for semiconducting applications such as an electron accepting material for organic photovoltaic cells and as a catalyst in biomimetic sensors. It may also be used in the fabrication of organic thin film transistors(OTFTs) and quartz crystal microbalance(QCM) based sensors.

General description

Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine(F16CuPc) is an organic molecule that can be used as an electron transporting material with good air-stability and an electron mobility of 0.11 cm2/Vs . It is majorly used in a variety of energy conservation based applications.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKBS8025V
MKBG1222V
MKBB6450
09698KJ
45996KH

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Fabrication of highly air-stable ambipolar thin-film transistors with organic heterostructure of F16CuPc and DH-alpha 6T.
Ye R, et al.
Solid-State Electron, 52(1), 60-62 (2008)
Agata Sabik et al.
The Journal of chemical physics, 149(14), 144702-144702 (2018-10-15)
We have utilized scanning tunneling microscopy (STM) and low energy electron diffraction to determine the structural properties of two types of metal-phthalocyanines (MPcs), i.e., cobalt-phthalocyanine (CoPc) and hexadecafluorinated copper-phthalocyanine (F16CuPc) on the Ag(100) surface. For coverage close to one monolayer
Tetra-tert-butyl copper phthalocyanine-based QCM sensor for toluene detection in air at room temperature.
Kumar A, et al.
Sensors and Actuators B, Chemical, 210(1), 398-407 (2015)
Thickness-dependent structural transitions in fluorinated copper-phthalocyanine (F16CuPc) films.
de Oteyza DG, et al.
Journal of the American Chemical Society, 128(47), 15052-15053 (2006)
Electroanalytical determination of bumetanide employing a biomimetic sensor for detection of doping in sports.
dos SR, et al.
Analytical Methods : Advancing Methods and Applications, 6(15), 5792-5798 (2014)
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