446424
3,5-Di-tert-butyl-4-hydroxybenzyl alcohol
97%
Synonym(s):
3,5-Di-tert-butyl-4-hydroxyphenylmethanol, 4-Hydroxymethyl-2,6-di-tert-butylphenol
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About This Item
Linear Formula:
HOC6H2[C(CH3)3]2CH2OH
CAS Number:
Molecular Weight:
236.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-815-6
MDL number:
Assay:
97%
Form:
solid
InChI key
HNURKXXMYARGAY-UHFFFAOYSA-N
InChI
1S/C15H24O2/c1-14(2,3)11-7-10(9-16)8-12(13(11)17)15(4,5)6/h7-8,16-17H,9H2,1-6H3
SMILES string
CC(C)(C)c1cc(CO)cc(c1O)C(C)(C)C
assay
97%
form
solid
mp
139-141 °C (lit.)
functional group
hydroxyl
Quality Level
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General description
3,5-di-tert-butyl-4-hydroxybenzyl alcohol also known as 4-Hydroxymethyl-2,6-di-tert-butylphenol that is commonly used as an antioxidant in the preparation of PMA-type bifunctional polymers.
Application
3,5-Di-tert-butyl-4-hydroxybenzyl alcohol can be used as a reactant to synthesize:
- 2,6-di-tert-butyl-4-(dodecylselanylmethyl)phenol and bis(3,5-di-tert-butyl-4-hydroxybenzyl) selenide by reacting with dodecaneselenolate and sodium selenide.
- Monomeric antioxidant by reacting with imidazole and N-[4-(chlorocarbonyl)phenyl]maleimide.
- Sulfur-containing butylated hydroxytoluene derivatives by reacting with aryl/alky dithiols.
- 3,5-Di-tert-butyl-4-hydroxybenzaldehyde by oxidation reaction using stabilized IBX.
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 3
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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X Guan et al.
Carcinogenesis, 16(10), 2575-2582 (1995-10-01)
The mouse pneumotoxicant and lung and liver tumor promoter butylated hydroxytoluene (BHT) was examined for its effects on gap junctional intercellular communication (GJIC) in mouse lung epithelial (C10) and rat liver epithelial (WB-F344) cell lines. GJIC, as measured by fluorescent
Melt-grafting of maleimides having hindered phenol group onto polypropylene.
Kim TH and Lee N.
Bull. Korean Chem. Soc., 24(12), 1809-1813 (2003)
K D Munkres
Mechanisms of ageing and development, 5(3), 163-169 (1976-05-01)
Clonal growth rate and cellular viability of an inositol-less mutant of Neurospora crassa decline rapidly during deprivation of dietary inositol. Dietary antioxidants, either nordihydroguaiaretic acid, vitamin E or 3,5-ditert.-butyl-4-hydroxybenzyl alcohol, protected cells and clones of the mutant from death and
Synthesis of new polymeric antioxidants.
Oh DR, et al.
Bull. Korean Chem. Soc., 22(6), 629-632 (2001)
The antioxidant activity of 3, 5-di-tert-butyl-4-hydroxybenzyl derivatives.
Kim DH and Kummerow FA.
Journal of the American Chemical Society, 39(3), 150-155 (1962)
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