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442712

Sigma-Aldrich

Lithium iron(III) oxide

greener alternative

95%

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Synonym(s):
Battery_Electrode_Material_Cathode, Lithium ferrite
Linear Formula:
LiFeO2
CAS Number:
12022-46-7
Molecular Weight:
94.78
MDL number:
MFCD00061442
UNSPSC Code:
26111700
PubChem Substance ID:
24867977
NACRES:
NA.23

Assay

95%

form

powder

mol wt

Mw 94.78 g/mol

composition

LiFeO2

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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particle size

<1 μm

density

1.9 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

, Enabling

SMILES string

[Li+].[O-][Fe]=O

InChI

1S/Fe.Li.2O/q;+1;;-1

InChI key

JXGGISJJMPYXGJ-UHFFFAOYSA-N

Related Categories

General description

Lithium iron(III) oxide is a class of electrode material that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiFeO2 can be used as a non-toxic cathode material with a specific capacity of ~120 mAhg−1 at a rate of 100 mAg−1. It can further be used in the fabrication of lithium-ion batteries and rechargeable batteries.
Studied for its use as a long-lived porous cathode in molten carbonate fuel cells.

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H362

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Lact.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Synthesis of tetrahedral LiFeO2 and its behavior as a cathode in rechargeable lithium batteries
Armstrong AR, et al.
Journal of the American Chemical Society, 130(11), 3554-3559 (2008)
Synthesis of nano-crystalline LiFeO2 material with advanced battery performance
Lee YS, et al.
Electrochemical Communications, 4(9), 727-731 (2002)
Synthesis, structure, and electrochemical properties of a new cathode material, LiFeO2, with a tunnel structure
Matsumura T, et al.
Journal of the Electrochemical Society, 149(12), A1509-A1513 (2002)
Chitosan nanoparticles: a new vehicle for the improvement of the delivery of drugs to the ocular surface. Application to cyclosporin A
De Campos AM, et al.
International Journal of Pharmaceutics, 224(1-2), 159-168 (2001)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)
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