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442585

Sigma-Aldrich

Pentafluorophenylmagnesium bromide solution

0.5 M in diethyl ether

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Synonym(s):
(Perfluorophenyl)magnesium bromide, 2,3,4,5,6-Pentafluorophenylmagnesium bromide, Bromo(pentafluorophenyl)magnesium
Linear Formula:
C6F5MgBr
CAS Number:
879-05-0
Molecular Weight:
271.27
Beilstein:
3611565
MDL number:
MFCD00015720
UNSPSC Code:
12352103
PubChem Substance ID:
24867918
NACRES:
NA.22

form

liquid

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

bp

34.6 °C

density

0.861 g/mL at 25 °C

SMILES string

Fc1c(F)c(F)c([Mg]Br)c(F)c1F

InChI

1S/C6F5.BrH.Mg/c7-2-1-3(8)5(10)6(11)4(2)9;;/h;1H;/q;;+1/p-1

InChI key

AXQVMJIDNDRSFM-UHFFFAOYSA-M

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Application

Employed in the synthesis of novel arsonic and arsinic acids as ligands for potential transition-metal ion extractants, and in the synthesis of polyfluoroaryl alkyl sulfides.

Signal Word

Danger

Hazard Statements

H224,H302,H314,H336

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

-40.0 °F

Flash Point(C)

-40 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Journal of Fluorine Chemistry, 73, 73-73 (1995)
Solvent Extr. Ion Exch., 14, 417-417 (1996)

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