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Merck
CN

434787

Polybutadiene

average Mn ~3,000 by VPO

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About This Item

Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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Product Name

Polybutadiene, average Mn ~3,000 by VPO

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

description

peroxide number <= 10 mval/kg

form

viscous liquid

mol wt

average Mn ~3,000 by VPO

composition

cis-1,4, 75%
trans-1,4, 24%
vinyl, 1%

refractive index

n20/D 1.524

viscosity

2,700-3,000 mPa.s(20 °C)(lit.)

mp

−6 °C

acid number

≤0.3 mg KOH/g

iodine value

420‑480 g/100g

transition temp

pour point ~−50 °C

solubility

aliphatic hydrocarbons: soluble

density

0.9 g/mL at 25 °C (lit.)

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Application

Co-reactant for air curing coatings.

Features and Benefits

Low viscosity liquid that undergoes polymerization in the presence of oxygen and free radical generators. Unsaponifiable drying oil. Improves water and chemical resistance.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Joan M Widin et al.
Journal of the American Chemical Society, 134(8), 3834-3844 (2012-01-28)
Controlled/"living" polymerizations and tandem polymerization methodologies offer enticing opportunities to enchain a wide variety of monomers into new, functional block copolymer materials with unusual physical properties. However, the use of these synthetic methods often introduces nontrivial molecular weight polydispersities, a
P S Brown et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13712-13719 (2012-09-13)
Two-dimensional hexagonally ordered honeycomb surfaces have been created by solvent casting polybutadiene films under controlled humidity. Subsequent CF(4) plasmachemical fluorination introduces cross-linking and surface texturing, leading to hierarchical surfaces with roughness on both the 10 μm (honeycomb) and micrometer (texturing)
Gregory P Robbins et al.
Langmuir : the ACS journal of surfaces and colloids, 26(17), 14089-14096 (2010-08-14)
The polymersome, a fully synthetic cell mimetic, is a tunable platform for drug delivery vehicles to detect and treat disease (theranostics). Here, we design a leuko-polymersome, a polymersome with the adhesive properties of leukocytes, which can effectively bind to inflammatory
Bounphanh Tonpheng et al.
Physical chemistry chemical physics : PCCP, 13(33), 15047-15054 (2011-07-22)
The thermal conductivity κ, heat capacity per unit volume ρc(p) and glass transition behaviour under pressure have been established for medium and high vinyl content polybutadiene PB with molecular weights 2600 and 100,000 and their highly cross-linked (ebonite) states obtained
Rachel Calvet et al.
Journal of chromatography. A, 1253, 164-170 (2012-07-24)
In this study, the coupling of IGC-ID analysis and carbon blacks impregnation with increasing ratios of polymer allow us to highlight the affinity of the polymer to the solid surface. The variations of the dispersive component of the surface energy

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