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433497

Sigma-Aldrich

Poly(propylene glycol), tolylene 2,4-diisocyanate terminated

average Mn ~2,300 (narrow MW distribution), isocyanate ~3.6 wt. %

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Synonym(s):
Polypropylene glycol-toluene diisocyanate copolymer, Tolylene diisocyanate-polypropylene glycol polymer
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

viscous liquid

Quality Level

mol wt

average Mn ~2,300 (narrow MW distribution)
degree of polymerization ~34

composition

isocyanate, ~3.6 wt. %

hardness

80 (Shore A, reacted with MOCA)

impurities

<0.1% residual TDI

refractive index

n20/D 1.4742

viscosity

≤1,700 cP(40 °C)(lit.)

density

1.05 g/mL at 25 °C

SMILES string

CC(O)CO.Cc1ccc(cc1N=C=O)N=C=O

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Application

Idler rollers and adhesive-handling pads.

Features and Benefits

Lower viscosity than conventional polyurethane oligomers. Aromatic isocyanate is more reactive than aliphatic isocyanate. Aromatic isocyanates are less light stable than aliphatic isocyanates.

Physical form

Polyurethane prepolymer.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup


Certificates of Analysis (COA)

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[Plombage of pathological pleural cavities].
V Ia Dzhugostran
Grudnaia khirurgiia (Moscow, Russia), (5)(5), 58-60 (1987-09-01)
E A Stepanov et al.
Grudnaia i serdechno-sosudistaia khirurgiia, (1)(1), 52-55 (1990-01-01)
The authors discuss experience in 168 operations for extirpation and segmental resection of affected bronchi in children with bronchiectases. To prevent recanalization of the bronchus after its segmental resection and to prevent the formation of an abscess in the isolated
[Excretory insufficiency of the pancreas after occlusion of the ductal system with glue].
V S Zemskov et al.
Vestnik khirurgii imeni I. I. Grekova, 138(3), 73-74 (1987-03-01)
P P Salov et al.
Vestnik khirurgii imeni I. I. Grekova, 146(3), 71-72 (1991-03-01)
The authors have suggested the presence of reflux regulating the relationship between the urinary bladder and vesicoureteral segment which was called the vesico-osteal reflex (VOR). An original method of diagnostics of VOR with the help of profilometry was developed. A
[Clinico-morphological characteristics of chronic pancreatitis in pancreatic duct occlusion using KL-3 glue].
V S Zemskov et al.
Klinicheskaia khirurgiia, (11)(11), 3-5 (1986-01-01)

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