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grade
technical grade
Quality Level
Assay
85%
mp
222-226 °C (dec.) (lit.)
SMILES string
[Na+].CS([O-])=O
InChI
1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1
InChI key
LYPGDCWPTHTUDO-UHFFFAOYSA-M
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General description
Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.
Signal Word
Warning
Hazard Statements
Hazard Classifications
Acute Tox. 4 Oral
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Conjugate addition of sodium methanesulfinate to vinyl pyridines and diazines for the synthesis of aliphatic sulfones.
Tetrahedron Letters, 50(17), 1928-1933 (2009)
Proceedings of the National Academy of Sciences of the United States of America, 109(46), 18719-18724 (2012-10-24)
Airborne particles affect human health and significantly influence visibility and climate. A major fraction of these particles result from the reactions of gaseous precursors to generate low-volatility products such as sulfuric acid and high-molecular weight organics that nucleate to form
Free radical biology & medicine, 6(5), 493-503 (1989-01-01)
A major impediment to the confirmation of free radical mechanisms in pathogenesis is a lack of direct, chemical evidence that oxygen centered free radicals actually arise in living tissues in quantities sufficient to cause serious damage. This investigation was conducted
Environmental science & technology, 36(23), 5155-5163 (2003-01-14)
Dimethyl sulfoxide (CH3S(O)CH3: DMSO) is an important product of dimethyl sulfide (CH3SCH3: DMS) photooxidation. The mechanism of the OH-radical initiated oxidation of DMSO is still highly uncertain and a major aim of recent studies has been to establish if methane
One-pot synthesis of aryl sulfoxides and sulfonium salts from sulfinic acid as a novel sulfurizing agent.
Chemical Communications (Cambridge, England), 17, 2099-2100 (1996)
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