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Sigma-Aldrich

Sodium methanesulfinate

technical grade, 85%

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Synonym(s):
Methanesulfinic acid sodium salt
Linear Formula:
CH3SO2Na
CAS Number:
Molecular Weight:
102.09
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

Assay

85%

mp

222-226 °C (dec.) (lit.)

SMILES string

[Na+].CS([O-])=O

InChI

1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1

InChI key

LYPGDCWPTHTUDO-UHFFFAOYSA-M

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General description

Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Conjugate addition of sodium methanesulfinate to vinyl pyridines and diazines for the synthesis of aliphatic sulfones.
Schaaf GM, et al.
Tetrahedron Letters, 50(17), 1928-1933 (2009)
Matthew L Dawson et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(46), 18719-18724 (2012-10-24)
Airborne particles affect human health and significantly influence visibility and climate. A major fraction of these particles result from the reactions of gaseous precursors to generate low-volatility products such as sulfuric acid and high-molecular weight organics that nucleate to form
C F Babbs et al.
Free radical biology & medicine, 6(5), 493-503 (1989-01-01)
A major impediment to the confirmation of free radical mechanisms in pathogenesis is a lack of direct, chemical evidence that oxygen centered free radicals actually arise in living tissues in quantities sufficient to cause serious damage. This investigation was conducted
Cecilia Arsene et al.
Environmental science & technology, 36(23), 5155-5163 (2003-01-14)
Dimethyl sulfoxide (CH3S(O)CH3: DMSO) is an important product of dimethyl sulfide (CH3SCH3: DMS) photooxidation. The mechanism of the OH-radical initiated oxidation of DMSO is still highly uncertain and a major aim of recent studies has been to establish if methane
One-pot synthesis of aryl sulfoxides and sulfonium salts from sulfinic acid as a novel sulfurizing agent.
Yamamoto K, et al.
Chemical Communications (Cambridge, England), 17, 2099-2100 (1996)

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