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Quality Level
Assay
98%
form
liquid
reaction suitability
core: germanium
reagent type: reductant
refractive index
n20/D 1.433 (lit.)
bp
121-122 °C/20 mmHg (lit.)
density
0.994 g/mL at 25 °C (lit.)
SMILES string
CC[GeH](CC)CC
InChI
1S/C6H16Ge/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
InChI key
LTLGQZPDSQYFSB-UHFFFAOYSA-N
Related Categories
General description
Triethylgermanium hydride (Ge(C2H5)3H) may be prepared by a three step process:
- Ge(C2H5)3Br reacted with Na to yield Ge2(C2H5)6
- Ge2(C2H5)6 treated with Li to form Ge(C2H5)3Li
- ammonolysis of Ge(C2H5)3Li to give the end product, Ge(C2H5)3H. 1
Application
Reagent undergoes hydrogermylation with alkyl propiolates to give triethylgermylacrylates.
Packaging
Packaged in glass bottles
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
Certificates of Analysis (COA)
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Journal of Organometallic Chemistry, 435, 257-257 (1992)
Dalton transactions (Cambridge, England : 2003), 45(43), 17495-17507 (2016-11-02)
The reaction of the silyl complex [Rh{Si(OEt)
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