All Photos(2)
Synonym(s):
Samarium(III) triflate, Trifluoromethanesulfonic acid samarium(III) salt
Linear Formula:
Sm(SO3CF3)3
CAS Number:
Molecular Weight:
597.57
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
reaction suitability
core: samarium
reagent type: catalyst
SMILES string
[Sm+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI
1S/3CHF3O3S.Sm/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChI key
DDCWGUIPLGMBPO-UHFFFAOYSA-K
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Application
A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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The Journal of Organic Chemistry, 59, 3590-3590 (1994)
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