425478
Sulfur trioxide
contains stabilizer, ≥99%
Synonym(s):
Sulfuric anhydride
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About This Item
Linear Formula:
SO3
CAS Number:
Molecular Weight:
80.06
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99%
Recommended Products
vapor density
2.8 (vs air)
Quality Level
vapor pressure
280 mmHg ( 25 °C)
Assay
≥99%
contains
stabilizer
reaction suitability
reagent type: oxidant
bp
44.7 °C (lit.)
mp
16.8 °C (lit.)
density
1.97 g/mL at 25 °C (lit.)
SMILES string
O=S(=O)=O
InChI
1S/O3S/c1-4(2)3
InChI key
AKEJUJNQAAGONA-UHFFFAOYSA-N
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General description
Sulfur trioxide (SO3) is an oxide of sulfur. It is released during the combustion of sulfur bearing fuels. Sulfur dioxide in the presence of vanadia catalyst oxidizes to form sulfur trioxide. The kinetics of this reaction has been studied. Density function theory and ab initio methods have been used to study the hydrolysis of SO3 to form sulfuric acid.
Application
Sulfur trioxide (SO3) may be used in the synthesis of methane sulfonic acid (MSA) by sulfonating methane.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Hydrolysis of sulfur trioxide to form sulfuric acid in small water clusters.
Larson LJ, et al.
J. Chem. Phys. , 112(20), 8830-8838 (2000)
Montu K Hazra et al.
Journal of the American Chemical Society, 133(43), 17444-17453 (2011-09-22)
Computational studies at the B3LYP/6-311++G(3df,3pd) and MP2/6-311++G(3df,3pd) levels are performed to explore the changes in reaction barrier height for the gas phase hydrolysis of SO(3) to form H(2)SO(4) in the presence of a single formic acid (FA) molecule. For comparison
Luguang Chen et al.
Environmental science & technology, 47(3), 1729-1734 (2013-01-11)
Sulfur emission from a Victorian brown coal was quantitatively determined through controlled experiments in a continuously fed drop-tube furnace under three different atmospheres: pyrolysis, oxy-fuel combustion, and carbon dioxide gasification conditions. The species measured were H(2)S, SO(2), COS, CS(2), and
M Thanou et al.
Journal of controlled release : official journal of the Controlled Release Society, 117(2), 171-178 (2006-12-23)
Chitosan has been shown to act on the mucosal epithelial barriers mainly when protonated at acidic pH values in which it is soluble. Soluble chitosan is able to improve the permeation and absorption of neutral to cationic macromolecules only, as
Yan Cao et al.
Environmental science & technology, 44(9), 3429-3434 (2010-04-13)
The formation of sulfur trioxide (SO(3)) in coal-fired utility boilers can have negative effects on boiler performance and operation, such as fouling and corrosion of equipment, efficiency loss in the air preheater (APH), increase in stack opacity, and the formation
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