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Sigma-Aldrich

Tetraamminepalladium(II) nitrate solution

10 wt. % in H2O, 99.99%

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Synonym(s):
Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate
Linear Formula:
Pd(NH3)4(NO3)2
CAS Number:
13601-08-6
Molecular Weight:
298.55
MDL number:
MFCD00011591
UNSPSC Code:
12161600
PubChem Substance ID:
24866533
NACRES:
NA.22

Quality Level

100

Assay

99.99%

form

liquid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

concentration

10 wt. % in H2O

density

1.03 g/mL at 25 °C

SMILES string

N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

WIDMMNCAAAYGKW-UHFFFAOYSA-N

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Application

Tetraamminepalladium(II)nitrate solution can be used as a palladium precursor to prepare:
  • Pd/C catalyst for the decarbonylation of heptanoic acid to 1-hexene.
  • Pd/Al2O3 catalyst for the decomposition of formic acid.
  • Pd/CNT catalyst for the dehalogenation of triclosan in water.

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H272,H315,H319

Hazard Classifications

Eye Irrit. 2 - Ox. Liq. 2 - Skin Irrit. 2

Supplementary Hazards

EUH001

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J P Berry
Journal of submicroscopic cytology, 19(1), 53-56 (1987-01-01)
Palladium salt has been used for some time in experimental therapy protocols; with this in mind, we carried out a study of the effect of tetramine dichloro-palladium (soluble salt) upon kidney cells. Using an electron microprobe, we were able to
J Ma
The Journal of general physiology, 102(6), 1031-1056 (1993-12-01)
The effects of ruthenium red and the related compounds tetraamine palladium (4APd) and tetraamine platinum (4APt) were studied on the ryanodine activated Ca2+ release channel reconstituted in planar bilayers with the immunoaffinity purified ryanodine receptor. Ruthenium red, applied at submicromolar

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