All Photos(2)
Synonym(s):
(Dimethylsulfide)gold(I) chloride
Linear Formula:
(CH3)2SAuCl
CAS Number:
Molecular Weight:
294.55
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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form
powder
Quality Level
reaction suitability
core: gold
reagent type: catalyst
SMILES string
Cl[Au].CSC
InChI
1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
InChI key
YQALRAGCVWJXGB-UHFFFAOYSA-M
Related Categories
Application
Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
It can also be used to synthesize:
- chloro(trimesitylphosphine)gold(I)
- gold(I) N-heterocyclic carbene (NHC) complexes
- bis(carbene)gold(I) complex of ferrocenyl complexes
- gold(I) acetylide complexes
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Find documentation for the products that you have recently purchased in the Document Library.
Synthesis and anticancer properties of gold (I) and silver (I) N-heterocyclic carbene complexes
Siciliano T J, et al.
Journal of Organometallic Chemistry, 696(5), 1066-1071 (2011)
Chloro (dimethyl sulfide) gold (I)
Jones P G, et al.
Acta Crystallographica Section C, Crystal Structure Communications, 44(12), 2089-2091 (1988)
Liquid-crystalline (lsonitrile) gold (I) acetylide complexes.
Kaharu T, et al.
Journal of Materials Chemistry, 5(4), 687-692 (1995)
Intermolecular [2+ 2] Cycloaddition of Alkynes with Alkenes Catalyzed by Gold (I)
de Orbe M E, et al.
Organic Syntheses, 93, 115-126 (2003)
A cytotoxic bis (carbene) gold (I) complex of ferrocenyl complexes: synthesis and structural characterisation.
Horvath U E, et al.
New. J. Chem., 32(3), 533-539 (2008)
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