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Merck
CN

418064

tert-Butyl hydroperoxide solution

5.0-6.0 M in nonane

Synonym(s):

1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

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About This Item

Linear Formula:
(CH3)3COOH
CAS Number:
75-91-2
Molecular Weight:
90.12
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24866199
MDL number:
MFCD00002130
Beilstein/REAXYS Number:
1098280

Key Documents

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Product Name

tert-Butyl hydroperoxide solution, 5.0-6.0 M in nonane

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

SMILES string

CC(C)(C)OO

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: oxidant

concentration

5.0-6.0 M in nonane

impurities

<4% water

refractive index

n20/D 1.399

density

0.817 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

200

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Related Categories

Application

Asymmetric Ketone Hydrogenation

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

target_organs

Central nervous system, Respiratory system

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 3

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCX1506
MKCX3193
MKCX1505
MKCW9351
MKCV6869

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Aldrichimica Acta, 12, 63-63 (1979)
Maxim O Ratnikov et al.
Journal of the American Chemical Society, 135(4), 1549-1557 (2013-01-10)
A general mechanism is proposed for transition metal-catalyzed oxidative Mannich reactions of N,N-dialkylanilines with tert-butyl hydroperoxide (TBHP) as the oxidant. The mechanism consists of a rate-determining single electron transfer (SET) that is uniform from 4-methoxy- to 4-cyano-N,N-dimethylanilines. The tert-butylperoxy radical
Qiong Tang et al.
Ultrasonics sonochemistry, 20(5), 1168-1175 (2013-03-30)
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The
Younghwa Kim et al.
Food chemistry, 137(1-4), 136-141 (2012-12-04)
Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)
Yury Minko et al.
Nature protocols, 8(4), 749-754 (2013-03-23)
This protocol describes a new approach for the preparation of stereodefined trisubstituted chiral enolate species, avoiding conventional asymmetric enolization of carbonyl compounds. This protocol was developed as a single-flask synthetic sequence and therefore does not require isolation or purification of
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