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414336

Sigma-Aldrich

Azetidine hydrochloride

97%

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Synonym(s):
Trimethyleneimine hydrochloride
Empirical Formula (Hill Notation):
C3H7N · HCl
CAS Number:
36520-39-5
Molecular Weight:
93.56
MDL number:
MFCD00191762
UNSPSC Code:
12352100
PubChem Substance ID:
24865934
NACRES:
NA.22

Quality Level

100

Assay

97%

mp

>300 °C (lit.)

SMILES string

Cl[H].C1CNC1

InChI

1S/C3H7N.ClH/c1-2-4-3-1;/h4H,1-3H2;1H

InChI key

HGQULGDOROIPJN-UHFFFAOYSA-N

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Related Categories

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

305.6 °F

Flash Point(C)

152 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Christopher S Dunkley et al.
Bioorganic & medicinal chemistry letters, 13(17), 2899-2901 (2003-11-13)
A series of compounds containing an N-(4'-substituted-3'-nitrophenyl)sydnone moiety with potential antitumor activity was prepared based on active analogues. The rationale behind the design of these compounds is presented along with the 4-step synthetic route to the derivatives in the 4'-position
Dongliang Chang et al.
Organic letters, 4(11), 1859-1862 (2002-05-25)
[reaction: see text] Hydroxylation of N-substituted azetidines 11 and 12 and piperidines 15-19 with Sphingomonas sp. HXN-200 gave 91-98% of the corresponding 3-hydroxyazetidines 13 and 14 and 4-hydroxypiperidines 20-24, respectively, with high activity and excellent regioselectivity. High yields and high
Synthesis of ornithine lactams via diastereoselective photocyclization of 2-amino-4-oxo-4-phenyl-butanoyl amines.
Lindemann U, et al.
Tetrahedron Asymmetry, 9(24), 4459-4473 (1998)
Valérian Gobé et al.
Organic letters, 16(20), 5438-5441 (2014-10-01)
1,5-/1,6-Allenals conjugated to an aromatic ring undergo a cyclization, in the presence of an amine, that leads to tricyclic compounds including the 1-aminotetralin scaffold. This domino process combines the in situ formation of the enamine and the cyclization affording the

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