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Merck
CN

412295

4-(Trifluoromethyl)phenylhydrazine

96%

Synonym(s):

1-(4-Trifluoromethylphenyl)hydrazine, 4-Trifluoromethylphenylhydrazine, [4-(Trifluoromethyl)phenyl]hydrazine, p-Trifluoromethylphenylhydrazine

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About This Item

Linear Formula:
CF3C6H4NHNH2
CAS Number:
368-90-1
Molecular Weight:
176.14
NACRES:
NA.22
PubChem Substance ID:
24865801
UNSPSC Code:
12352100
MDL number:
MFCD00042508
Assay:
96%

Key Documents

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InChI

1S/C7H7F3N2/c8-7(9,10)5-1-3-6(12-11)4-2-5/h1-4,12H,11H2

SMILES string

NNc1ccc(cc1)C(F)(F)F

InChI key

DBNLGTYGKCMLLR-UHFFFAOYSA-N

assay

96%

bp

118-122 °C/17 mmHg (lit.)

mp

63-65 °C (lit.)

functional group

fluoro, hydrazine

storage temp.

2-8°C

Quality Level

200

Related Categories

General description

4-(Trifluoromethyl)phenylhydrazine participates as phenylhydrazine-based reductant containing fluorine atoms in the one-step reduction and functionalization of graphene oxide.

Application

4-(Trifluoromethyl)phenylhydrazine may be used for the synthesis of 2-iodo-9-trifluoromethyl-paullone.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM8051
BCCN0293
BCCL7532
BCCJ9382
BCCH1287

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C Kunick et al.
Bioorganic & medicinal chemistry letters, 10(6), 567-569 (2000-03-31)
9-Trifluoromethyl-paullones with a carbon chain in the 2-position were synthesized by palladium-catalyzed coupling reactions of a 2-iodoprecursor with terminal alkenes or alkynes, respectively. The introduction of a 2-cyanoethyl substituent led to a significant enhancement of CDK1/cyclin B inhibiting property and
Su-Hyeon Kim et al.
Nanoscale, 6(13), 7183-7187 (2014-05-08)
A one-step reduction and functionalization of graphene oxide (FrGO) was easily achieved using a novel phenylhydrazine-based reductant containing fluorine atoms, which can induce p-type doping due to its high electronegativity. The FrGO-based OPV exhibited a high power conversion efficiency of

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