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411167

Sigma-Aldrich

Bisphenol A glycerolate (1 glycerol/phenol) diacrylate

contains MEHQ as inhibitor

Synonym(s):

2,2-Bis[4-(3-acryloyloxy-2-hydroxypropoxy)phenyl]propane, 2,2-Bis[acryloyloxy(2′-hydroxypropyloxy)phenyl]propane, Bisphenol A glycerolate diacrylate

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About This Item

Empirical Formula (Hill Notation):
C27H32O8
CAS Number:
Molecular Weight:
484.54
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

contains

MEHQ as inhibitor
250-500 ppm MEHQ as inhibitor

Quality Level

refractive index

n20/D 1.557 (lit.)

viscosity

2000-4000 cP(65 °C)(lit.)

acid number

<5 mg KOH/g

density

1.18 g/mL at 25 °C (lit.)

SMILES string

CC(C)(c1ccc(OCC(O)COC(=O)C=C)cc1)c2ccc(OCC(O)COC(=O)C=C)cc2

InChI

1S/C27H32O8/c1-5-25(30)34-17-21(28)15-32-23-11-7-19(8-12-23)27(3,4)20-9-13-24(14-10-20)33-16-22(29)18-35-26(31)6-2/h5-14,21-22,28-29H,1-2,15-18H2,3-4H3

InChI key

VZTQQYMRXDUHDO-UHFFFAOYSA-N

Related Categories

Application

UV curable cross-linking agent. Component of curable inks, coatings, varnishes and lacquers.

Features and Benefits

High viscosity, non-volatile, difunctional acrylate. Gives fast cure speeds, low odor and low volatility.

Physical form

epoxy acrylate oligomer

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Skin Sens. 1

WGK

WGK 3

Flash Point(F)

235.4 °F

Flash Point(C)

113 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Han N Lee et al.
American journal of contact dermatitis : official journal of the American Contact Dermatitis Society, 13(3), 108-115 (2002-08-08)
The study's objective was 2-fold: first, to evaluate the potential cross-reactivity between Bis-A epoxy resins and epoxy acrylates and second, to study the cross reactivity between Bis-A epoxy resins and newer Bis-F epoxy resins in patients with allergic contact dermatitis
Kristiina Aalto-Korte et al.
Contact dermatitis, 61(1), 9-21 (2009-08-08)
Contact allergy to epoxy (meth)acrylates, 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy) phenyl]propane (bis-GMA), 2,2-bis[4-(2-hydroxy-3-acryloxypropoxy)phenyl]-propane (bis-GA), 2,2-bis[4-(methacryl-oxyethoxy)phenyl] propane (bis-EMA), 2,2-bis[4-(methacryloxy)phenyl]-propane (bis-MA), and glycidyl methacrylate (GMA) is often manifested together with contact allergy to diglycidyl ether of bisphenol A (DGEBA) epoxy resin. To analyse patterns of concomitant
Li Li et al.
Electrophoresis, 33(16), 2591-2597 (2012-08-18)
Manufacturing materials are an essential element for the fabrication of microfluidic chips. PDMS, the most widely used polymeric material, is associated with apparent disadvantages such as hydrophobic nature, while other materials also suffer from some limitations. In this paper, a
L Kanerva et al.
Contact dermatitis, 14(2), 80-84 (1986-02-01)
A dental assistant developed sensitivity to dental restorative materials within 3 months of starting to use them. They contained the epoxy acrylate BIS-GMA, which is the most commonly used dimethacrylate monomer in dental composite restorations. She was positive to a
B Bjorkner et al.
Contact dermatitis, 10(5), 286-304 (1984-05-01)
Most composite materials in dentistry used today, contain resins based on dimethacrylates. BIS-GMA [2,2-bis-(4-(2-hydroxy-3-methacryloxypropoxy)phenyl)propane], the addition reaction product of bisphenol A and glycidyl methacrylate or an epoxy resin and methacrylic acid, is used most extensively. More recently, dimethacrylates based on

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