410136
Samarium(III) isopropoxide
99.9% trace metals basis
Synonym(s):
Samarium triisopropoxide, Tris(isopropoxy)samarium
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About This Item
Linear Formula:
Sm[OCH(CH3)2]3
CAS Number:
Molecular Weight:
327.62
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99.9% trace metals basis
form
powder and chunks
reaction suitability
core: samarium
reagent type: catalyst
SMILES string
CC(C)O[Sm](OC(C)C)OC(C)C
InChI
1S/3C3H7O.Sm/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI key
HJCRVWSKQNDSPZ-UHFFFAOYSA-N
Application
Used with a dinucleating Schiff base ligand in a catalytic asymmetric nitro-Mannich reaction.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex.
Shinya Handa et al.
Journal of the American Chemical Society, 129(16), 4900-4901 (2007-03-31)
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