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407739

Sigma-Aldrich

L-tert-Leucinol

98%, for peptide synthesis

Synonym(s):

(S)-2-Amino-3,3-dimethyl-1-butanol

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About This Item

Linear Formula:
(CH3)3CCH(NH2)CH2OH
CAS Number:
112245-13-3
Molecular Weight:
117.19
Beilstein:
3600321
MDL number:
MFCD00192250
UNSPSC Code:
12352209
PubChem Substance ID:
24865483
NACRES:
NA.22

product name

L-tert-Leucinol, 98%

Assay

98%

optical activity

[α]26/D +37°, c = 1.5 in ethanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

30-34 °C (lit.)

density

0.9 g/mL at 25 °C (lit.)

application(s)

peptide synthesis

SMILES string

CC(C)(C)[C@H](N)CO

InChI

1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1

InChI key

JBULSURVMXPBNA-RXMQYKEDSA-N

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Related Categories

Application

Useful amino acid employed in various asymmetric reactions.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron Letters, 45, 5649-5649 (2004)
Tetrahedron, 60, 4459-4473 (2004)
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction

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