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Merck
CN

406023

Diethylzinc solution

1.0 M in heptane

Synonym(s):

Zincdiethyl

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About This Item

Linear Formula:
(C2H5)2Zn
CAS Number:
557-20-0
Molecular Weight:
123.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24865350
MDL number:
MFCD00009021
Beilstein/REAXYS Number:
3587207

Key Documents

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Product Name

Diethylzinc solution, 1.0 M in heptane

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

SMILES string

CC[Zn]CC

InChI key

HQWPLXHWEZZGKY-UHFFFAOYSA-N

form

liquid

concentration

1.0 M in heptane

bp

98 °C

density

0.74 g/mL at 25 °C

Quality Level

100

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Application

Diethylzinc solution can be used in the synthesis of:
  • Bis(pyridylpyrrolyl)zinc luminescent complexes.
  • A versatile building block, 5-(ketoaryl)thiazole.
  • ZnxCd1-xSe nanocrystals having high luminescence properties.

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

EUH014

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

12.2 °F - closed cup

flash_point_c

-11 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SHBS7875
SHBS7874
SHBS5978
SHBR7171
SHBR7170

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Composition-Tunable ZnxCd1-xSe nanocrystals with high luminescence and stability.
Xinhua Z, et al.
Journal of the American Chemical Society, 125(28), 8589-8594 (2003)
Practical synthesis of a highly functionalized thiazole ketone.
Frey LF, et al.
Tetrahedron, 59(33), 6363-6373 (2003)
Pyridylpyrrolides as alternatives to cyclometalated phenylpyridine ligands: synthesis and characterization of luminescent zinc and boron pyridylpyrrolide complexes.
Klappa JJ, et al.
Dalton Transactions, 883-891 (2004)
Su-Xi Wang et al.
Chemical & pharmaceutical bulletin, 55(7), 1011-1013 (2007-07-03)
Newly synthesized polymer-supported chiral amino alcohol catalysts 5a and 5b have been proved to be effective for the enantioselective addition of diethylzinc to aldehydes, affording the corresponding sec-alcohols in moderate enantiomeric excesses with good to excellent yields. The recycled catalyst
Yan Yin et al.
The Journal of organic chemistry, 72(15), 5731-5736 (2007-06-22)
Intramolecular hydroamination of alkynyl amides was effected by a catalytic amount of Et2Zn (20 mol %) to form indole derivatives, and a tandem cyclization/nucleophilic addition procedure involving reaction of the indole zinc salt intermediate with acid chlorides or halides was
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