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399396

Benzoin

Name: Benzoin
Brand: ALDRICH

purified by sublimation, ≥99.5%

Synonym(s):

α-Hydroxy-α-phenylacetophenone, α-Hydroxybenzyl phenyl ketone, 2-Hydroxy-2-phenylacetophenone

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About This Item

Linear Formula:

C₆H₅CH(OH)COC₆H₅

CAS Number:

119-53-9

Molecular Weight:

212.24

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24864811

EC Number:

204-331-3

Beilstein/REAXYS Number:

391839

MDL number:

MFCD00004496

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Properties

assay

≥99.5%

form

powder

purified by

sublimation

bp

194 °C/12 mmHg (lit.)

mp

134-138 °C (lit.)

SMILES string

OC(c1ccccc1)C(=O)c2ccccc2

InChI

1S/C14H12O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13,15H

InChI key

ISAOCJYIOMOJEB-UHFFFAOYSA-N

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

Description

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Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Asymmetric autocatalysis: triggered by chiral isotopomer arising from oxygen isotope substitution.

Tsuneomi Kawasaki et al.

Angewandte Chemie (International ed. in English), 50(35), 8131-8133 (2011-07-16)

Trigger happy: chiral oxygen isotopomers of hydrobenzoin ([(18)O](R)-1 and [(18)O](S)-1) acted as chiral triggers to induce the enantioselective addition of iPr(2)Zn to pyrimidine-5-carbaldehyde. An extremely small chiral influence arising from the presence of the oxygen isotope ((18)O) is amplified through

A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.

Javier Izquierdo et al.

Angewandte Chemie (International ed. in English), 51(47), 11686-11698 (2012-10-18)

N-Heterocyclic carbene (NHC) catalyzed transformations have emerged as powerful tactics for the construction of complex molecules. Since Stetter's report in 1975 of the total synthesis of cis-jasmon and dihydrojasmon by using carbene catalysis, the use of NHCs in total synthesis

Structures and reactivities of O-methylated Breslow intermediates.

Biplab Maji et al.

Angewandte Chemie (International ed. in English), 51(41), 10408-10412 (2012-09-13)

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Global Trade Item Number

SKU	GTIN
399396-5G	04061833372449