398306
Palladium(II) sulfide
99.9% trace metals basis
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About This Item
Linear Formula:
PdS
CAS Number:
Molecular Weight:
138.49
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
235-190-6
MDL number:
InChI key
NRUVOKMCGYWODZ-UHFFFAOYSA-N
InChI
1S/Pd.S
SMILES string
S=[Pd]
assay
99.9% trace metals basis
form
solid
reaction suitability
reagent type: catalyst
core: palladium
density
6.6 g/mL at 25 °C (lit.)
General description
Palladium sulfide can be formed from allyl palladium dithiocarbamates and dithiolate complexes by metal organic chemical vapor deposition (MOCVD). Enthalpy of formation of the Pd-S system has been investigated by mixing calorimetry method.
Application
PdS organosol can be prepared by reacting the metal acetate with hydrogen sulfide. These organo sols may be further utilized to form polymer metal sulfide composites. Palladium sulfide may be used to catalyze the hydrogenation of thiopene.
Packaging
Packaged in glass bottles
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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New organosols of nickel sulfides, palladium sulfides, manganese sulfide, and mixed metal sulfides and their use in preparation of semiconducting polymer-metal sulfide composites.
Yamamoto T, et al.
Colloid and Polymer Science, 269(10), 969-971 (1991)
Enthalpies of formation of the palladium sulphides
Zubkov A, et al.
The Journal of Chemical Thermodynamics, 30(5), 571-581 (1998)
Kinetic study of catalytic hydrogenation of thiophene on a palladium sulfide catalyst.
Ermakova A, et al.
Kinetics and Catalysis, 43(4), 528-536 (2002)
Allyl palladium dithiocarbamates and related dithiolate complexes as precursors to palladium sulfides
Birri A, et al.
Journal of Organometallic Chemistry, 692(12), 2448- 2455 (2007)
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