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About This Item
Linear Formula:
PdS
CAS Number:
Molecular Weight:
138.49
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Recommended Products
Assay
99.9% trace metals basis
form
solid
reaction suitability
reagent type: catalyst
core: palladium
density
6.6 g/mL at 25 °C (lit.)
SMILES string
S=[Pd]
InChI
1S/Pd.S
InChI key
NRUVOKMCGYWODZ-UHFFFAOYSA-N
General description
Palladium sulfide can be formed from allyl palladium dithiocarbamates and dithiolate complexes by metal organic chemical vapor deposition (MOCVD). Enthalpy of formation of the Pd-S system has been investigated by mixing calorimetry method.
Application
PdS organosol can be prepared by reacting the metal acetate with hydrogen sulfide. These organo sols may be further utilized to form polymer metal sulfide composites. Palladium sulfide may be used to catalyze the hydrogenation of thiopene.
Packaging
Packaged in glass bottles
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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New organosols of nickel sulfides, palladium sulfides, manganese sulfide, and mixed metal sulfides and their use in preparation of semiconducting polymer-metal sulfide composites.
Yamamoto T, et al.
Colloid and Polymer Science, 269(10), 969-971 (1991)
Allyl palladium dithiocarbamates and related dithiolate complexes as precursors to palladium sulfides
Birri A, et al.
Journal of Organometallic Chemistry, 692(12), 2448- 2455 (2007)
Kinetic study of catalytic hydrogenation of thiophene on a palladium sulfide catalyst.
Ermakova A, et al.
Kinetics and Catalysis, 43(4), 528-536 (2002)
Enthalpies of formation of the palladium sulphides
Zubkov A, et al.
The Journal of Chemical Thermodynamics, 30(5), 571-581 (1998)
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