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Sigma-Aldrich

2-Aminoterephthalic acid

99%

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Synonym(s):
2-Aminobenzene-1,4-dicarboxylic acid
Linear Formula:
H2NC6H3-1,4-(CO2H)2
CAS Number:
10312-55-7
Molecular Weight:
181.15
Beilstein:
2805625
MDL number:
MFCD00134536
UNSPSC Code:
12352106
PubChem Substance ID:
24863787
NACRES:
NA.22

Quality Level

100

Assay

99%

form

powder, crystals or chunks

reaction suitability

reaction type: solution phase peptide synthesis

mp

324 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

Nc1cc(ccc1C(O)=O)C(O)=O

InChI

1S/C8H7NO4/c9-6-3-4(7(10)11)1-2-5(6)8(12)13/h1-3H,9H2,(H,10,11)(H,12,13)

InChI key

GPNNOCMCNFXRAO-UHFFFAOYSA-N

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Application

2-Aminoterephthalic acid can be used to synthesize:
  • Lanthanide coordination polymers with 1,10-phenanthroline by hydrothermal method.
  • Blue-emitting derivatives of 2-aminoterephthalic acid.
  • Amino-functionalized Zr-terephthalate (UiO-66), an excellent catalyst for selective synthesis of jasminaldehyde.
  • IRMOF-3, a zinc aminoterephthalate metal-organic framework useful as a catalyst for the Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate.
  • Polymeric composite membrane with excellent CO2 separation capabilities.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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An amino-modified Zr-terephthalate metal?organic framework as an acid?base catalyst for cross-aldol condensation
Vermoortele F, et al.
Chemical Communications (Cambridge, England), 47(5), 1521-1523 (2011)
Weiwei Zhao et al.
PloS one, 12(6), e0178513-e0178513 (2017-06-06)
UiO-66 analogues are good candidates as stationary phase in HPLC because of their chemical/thermal stability, large surface area, and two cage structures. Here, two UiO-66 analogues, UiO-66-NH2 and UiO-67, were synthesized and used as stationary phase in HPLC to evaluate
On the photostability of some blue-emitting derivatives of 2-aminoterephthalic acid and their copolymers with methyl methacrylate
Miladinova P, et al.
Polymer Degradation and Stability, 98(11), 2347-2350 (2013)
Qin Zhang et al.
Molecules (Basel, Switzerland), 23(8) (2018-08-22)
In this study, quaternary-ammonium-functionalized metal⁻organic frameworks (MOFs) Et-N-Cu(BDC-NH₂)(DMF), were prepared, characterized, and applied for the highly effective removal of metal cyanide complexes, including Pd(CN)₄²-, Co(CN)₆³-, and Fe(CN)₆³-. Batch studies were carried out, and the maximum adsorption capacities of Pd(II), Co(III)
Farhad Ahmadijokani et al.
Dalton transactions (Cambridge, England : 2003), 48(36), 13555-13566 (2019-07-30)
Mixed-matrix membranes (MMMs) are promising candidates for carbon dioxide separation. However, their application is limited due to improper dispersion of fillers within the polymer matrix, poor interaction of fillers with polymer chains, and formation of defects and micro-voids at the
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