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Sigma-Aldrich

Iron(III) phthalocyanine chloride

Dye content ~95 %

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Synonym(s):
Phthalocyanine iron(III) monochloride salt
Empirical Formula (Hill Notation):
C32H16ClFeN8
CAS Number:
14285-56-4
Molecular Weight:
603.82
Beilstein:
1200456
EC Number:
238-199-3
MDL number:
MFCD00134503
UNSPSC Code:
12352103
PubChem Substance ID:
24863671
NACRES:
NA.23

composition

Dye content, ~95%

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

λmax

654 nm

SMILES string

Cl[Fe]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.ClH.Fe/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;;/h1-16H;1H;/q-2;;+3/p-1

InChI key

LFECRQMMUVBGDC-UHFFFAOYSA-M

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Application

Iron catalyst for highly stereoselective C-H Amination reactions

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Shauna M Paradine et al.
Journal of the American Chemical Society, 134(4), 2036-2039 (2012-01-21)
A highly selective C-H amination reaction under iron catalysis has been developed. This novel system, which employs an inexpensive, nontoxic [Fe(III)Pc] catalyst (typically used as an industrial ink additive), displays a strong preference for allylic C-H amination over aziridination and

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