All Photos(2)

Documents

373729

Molybdenum(VI) tetrachloride oxide

Name: Molybdenum(VI) tetrachloride oxide
Brand: ALDRICH

97%

Synonym(s):

Molybdenum chloride oxide, Molybdenum oxide chloride, Molybdenum oxytetrachloride, Molybdenum tetrachloride monoxide, Molybdenum(VI) oxychloride, Tetrachlorooxomolybdenum

Sign Into View Organizational & Contract Pricing

All Photos(2)

About This Item

Linear Formula:

MoOCl₄

CAS Number:

13814-75-0

Molecular Weight:

253.75

MDL number:

MFCD00014222

UNSPSC Code:

12161600

PubChem Substance ID:

24863256

NACRES:

NA.22

Quality Level

100

Assay

97%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: molybdenum

storage temp.

2-8°C

SMILES string

Cl[Mo](Cl)(Cl)(Cl)=O

InChI

1S/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4

InChI key

UYEGPKGLVUUIGD-UHFFFAOYSA-J

Related Categories

Transition Metal Catalysts

Application

Molybdenum(VI) tetrachloride oxide can be used:

To prepare a binary metal catalyst (MoOCl₄-n-BuLi) for the living polymerization of various acetylenes.
As an oxidant in the aromatization of various Hantzsch-1,4-dihydropyridines.
As a molybdenum (Mo) precursor to prepare nafion-Mo composite material, which is used as a catalyst for the preparation of nitrones by reacting primary amines with aldehydes.

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Nafion supported molybdenum oxychloride: Recyclable catalyst for one-pot synthesis of nitrones via direct condensation/oxidation of primary amines and aldehydes using UHP as oxidant

Singh B, et al.

Green Chemistry, 11(12), 1941-1944 (2009)

Living Polymerization of Substituted Acetylenes by a Novel Binary Catalyst, MoOCl4- n-BuLi

Hayano S and Masuda T

Macromolecules, 31(10), 3170-3174 (1998)

Hayano, S. Masuda, T.

Macromolecules, 31, 3170-3170 (1998)

Remarkably fast and selective aromatization of Hantzsch esters with MoOCl4 and MoCl5: a chemical model for possible biologically relevant properties of molybdenum-containing enzymes.

Mladen Litvić et al.

Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)

Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose

Articles

Nanostructured Materials Through Ultrasonic Spray Pyrolysis

The diversity of applications and nanostructured materials accessible using ultrasonic spray methods are highlighted in this article.

Nanostructured Materials via Ultrasonic Spray Pyrolysis

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service