367826
1-(p-Toluenesulfonyl)azetidine
97%
Synonym(s):
1-Tosylazetidine
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About This Item
Empirical Formula (Hill Notation):
C10H13NO2S
CAS Number:
Molecular Weight:
211.28
Beilstein:
177046
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
solid
mp
119-122 °C (lit.)
SMILES string
Cc1ccc(cc1)S(=O)(=O)N2CCC2
InChI
1S/C10H13NO2S/c1-9-3-5-10(6-4-9)14(12,13)11-7-2-8-11/h3-6H,2,7-8H2,1H3
InChI key
VKCBXONEZGIOSP-UHFFFAOYSA-N
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General description
1-(p-Toluenesulfonyl)azetidine is a heterocyclic building block. Ag(I)-catalyzed ring-opening of 1-(p-toluenesulfonyl)azetidine (N-tosylazetidine) with alcohols, amines, thiols and related tethered 1,2-ethane dinucleophiles has been reported.
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Milan Bera et al.
The Journal of organic chemistry, 76(5), 1475-1478 (2011-02-05)
[Ag(COD)(2)]PF(6) catalyzes the ring-opening of N-tosylaziridines and -azetidines with alcohols, amines, thiols, and related tethered 1,2-ethane dinucleophiles. Initial rate studies and DFT-based evaluation of stepwise energetics suggest an inverse relationship between the nucleophilic reactivity of a heteroatom donor and its
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