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Merck
CN

364673

Ethylmagnesium bromide solution

1.0 M in THF

Synonym(s):

EtMgBr solution

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About This Item

Linear Formula:
CH3CH2MgBr
CAS Number:
925-90-6
Molecular Weight:
133.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24862450
MDL number:
MFCD00000043
Beilstein/REAXYS Number:
3587203

Key Documents

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Product Name

Ethylmagnesium bromide solution, 1.0 M in THF

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

SMILES string

CC[Mg]Br

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

form

liquid

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

density

1.010 g/mL at 25 °C

Quality Level

100

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Application

Ethylmagnesium bromide solution can be used in Grignard reaction and to synthesize other Grignard reagents.

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid.

Packaging

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Respiratory system

supp_hazards

EUH014,EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

23.0 °F - closed cup

flash_point_c

-5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SHBS6959
SHBR8067
SHBQ3094
SHBP2174
SHBP6970

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An improved synthesis of (+)-3, 4-O-isopropylidene butyne.
Jiang B
Synthetic Communications, 25(22), 3641-3645 (1995)
Replacement of the lactone moiety on podophyllotoxin and steganacin analogues with a 1, 5-disubstituted 1, 2, 3-triazole via ruthenium-catalyzed click chemistry.
Imperio D
Bioorganic & Medicinal Chemistry, 15(21), 6748-6757 (2007)
D R Hwang et al.
Nuclear medicine and biology, 27(6), 533-539 (2000-11-01)
Imaging neuroreceptors with radiolabeled agonists might provide valuable information on the in vivo agonist affinity states of receptors of interest. We report here the radiosynthesis, biodistribution in rodents, and imaging studies in baboons of [(11)C]-labeled (-)-N-propyl-norapomorphine [(-)-NPA]. (-)-[(11)C]NPA was prepared
M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
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