363901
2-Chloro-2-propen-1-ol
technical grade, 90%
Synonym(s):
2-Chloroallyl alcohol
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About This Item
Linear Formula:
H2C=C(Cl)CH2OH
CAS Number:
Molecular Weight:
92.52
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
grade
technical grade
Quality Level
Assay
90%
form
liquid
refractive index
n20/D 1.459 (lit.)
bp
133-134 °C (lit.)
density
1.162 g/mL at 25 °C (lit.)
SMILES string
OCC(Cl)=C
InChI
1S/C3H5ClO/c1-3(4)2-5/h5H,1-2H2
InChI key
OSCXYTRISGREIM-UHFFFAOYSA-N
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General description
2-Chloro-2-propen-1-ol is reported to undergo photodissociation at 193nm to generate CH2CCH2OH radical intermediate. 2-Chloro-2-propen-1-ol is formed as major product during base mediated reaction of 1,2,3-trichloropropane. 2-Chloro-2-propen-1-ol is reported to react with phosphorus trichloride to yield phosphorous esters, while with phosphory chloride it yields phosphoric ester.
Application
2-Chloro-2-propen-1-ol (2-chloropropenol) may be employed as carbon supplement for the growth of Pseudomonas strains. It may be used in the preparation of 2-(4-octylphenyl)prop-2-en-1-ol.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
WGK
WGK 3
Flash Point(F)
129.2 °F
Flash Point(C)
54 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Arjun S Raman et al.
The Journal of chemical physics, 127(15), 154316-154316 (2007-10-24)
These velocity map imaging experiments characterize the photolytic generation of one of the two radical intermediates formed when OH reacts via an addition mechanism with allene. The CH2CCH2OH radical intermediate is generated photolytically from the photodissociation of 2-chloro-2-propen-1-ol at 193
Derivatives of phosphorus acids and 2-chloro-2-propen-1-ol.
Arbuzov BA, et al.
Russian Chemical Bulletin, 16(6), 1233-1238 (1967)
Joanna Drzeżdżon et al.
Scientific reports, 8(1), 2315-2315 (2018-02-06)
The new type of catalysts designed for the olefin derivatives polymerization has been synthetized. The novel catalysts are chromium(III) salt type complexes composed of both organic cation and anion, i.e. [Cr(dipic)2][Cr(bipy)(dipic)H2O]∙2H2O and [Cr(dipic)2]Hdmbipy∙2.5 H2O. The compositions of these complexes have
J J van der Waarde et al.
Applied and environmental microbiology, 59(2), 528-535 (1993-02-01)
Three Pseudomonas strains capable of utilizing 2-chloroallylalcohol (2-chloropropenol) as the sole carbon source for growth were isolated from soil. The fastest growth was observed with strain JD2, with a generation time of 3.6 h. Degradation of 2-chloroallylalcohol was accompanied by
Kinetic studies of the homogeneous abiotic reactions of several chlorinated aliphatic compounds in aqueous solution.
Pagan M, et al.
Applied Geochemistry, 13(6), 779-785 (1998)
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