359483
(Methylthio)acetic acid
99%
Synonym(s):
(Methylmercapto)acetic acid
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About This Item
Linear Formula:
CH3SCH2COOH
CAS Number:
Molecular Weight:
106.14
Beilstein:
1740201
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
liquid
refractive index
n20/D 1.495 (lit.)
bp
130-131 °C/27 mmHg (lit.)
mp
13-14 °C (lit.)
density
1.219 g/mL at 25 °C (lit.)
SMILES string
CSCC(O)=O
InChI
1S/C3H6O2S/c1-6-2-3(4)5/h2H2,1H3,(H,4,5)
InChI key
HGTBAIVLETUVCG-UHFFFAOYSA-N
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General description
Formation of complexes of methyl thioacetate and copper(II) has been investigated. (Methylthio)acetic acid is an irreversible inhibitor of sarcosine oxidase and is effective in preventing the complete enzyme inactivation during modification.
Application
(Methylthio)acetic acid may be used in the synthesis of (5S,6S,8S)-8-acetoxy-6-(3,4-methylenedioxyphenyl)-1-[(methylthio)-acetyl]-1-azaspiro[4.4]nonane.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Jason A Berberich et al.
Acta biomaterialia, 1(2), 173-181 (2006-05-17)
The determination of creatinine levels in biological fluids is an increasingly important clinical requirement. Amperometric biosensors have been developed based on a three-enzyme system which converts creatinine to amperometrically measurable hydrogen peroxide. The development of the amperometric creatinine biosensor has
(METHYLTHIO) ACETATE AND (TERT BUTYLTHIO) ACETATE COMPLEXES OF COPPER (II).
Sandell A.
Acta Chemica Scandinavica, 25(8), 3172-3172 (1971)
M Ikeda et al.
Chemical & pharmaceutical bulletin, 47(7), 983-987 (1999-08-06)
A formal total synthesis of (-)-cephalotaxine (1) has been achieved. The key step is an intramolecular aldol condensation of the diketone 9, which in turn was obtained in three steps from the azabicyclic compound 6 derived from D-proline according to
P Trickey et al.
Structure (London, England : 1993), 7(3), 331-345 (1999-06-16)
Monomeric sarcosine oxidases (MSOXs) are among the simplest members of a recently recognized family of eukaryotic and prokaryotic enzymes that catalyze similar oxidative reactions with various secondary or tertiary amino acids and contain covalently bound flavins. Other members of this
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