359009
Cerium(IV) sulfate
powder
Synonym(s):
Ceric sulfate, Cerium disulfate
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About This Item
Linear Formula:
Ce(SO4)2
CAS Number:
Molecular Weight:
332.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-029-5
MDL number:
Product Name
Cerium(IV) sulfate,
InChI key
VZDYWEUILIUIDF-UHFFFAOYSA-J
InChI
1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4
SMILES string
[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
form
powder
reaction suitability
core: cerium, reagent type: catalyst
density
3.01 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
Cerium(IV) sulfate can be used to catalyze:
- Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
- Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
- Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.
Reactant for:
- Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions
- Oxidizing agent
Other Notes
may contain excess sulfate
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Cerimetric determination of catecholamines.
M I Walash et al.
Journal de pharmacie de Belgique, 39(2), 88-92 (1984-03-01)
Ceric-sulfate-catalyzed synthesis of 14-aryl-or 14-alkyl-14 H-dibenzo [aj] xanthene under conventional heating and microwave irradiation.
Selvam N P, et al.
Canadian Journal of Chemistry, 85(11), 989-995 (2007)
Cerium catalyzed selective oxidation of secondary alcohols in the presence of primary ones.
Tomioka H, et al.
Tetrahedron Letters, 23(5), 539-542 (1982)
Hidayat Hussain et al.
Journal of Asian natural products research, 17(7), 733-737 (2015-01-07)
Phytochemical investigation of the endophytic fungus Microdiplodia sp. afforded a new m-anisaldehyde derivative named microdiplanol (1) and a new 24-methylcholestanol derivative named microdiplane (2). Their structures were confirmed by a comprehensive analysis of 1D and 2D NMR and mass spectrometric
Alaa S Amin et al.
Journal of AOAC International, 92(2), 382-386 (2009-06-03)
Three simple, accurate, and sensitive colorimetric methods for the determination of cimetidine (Cim) in pure form, in dosage forms, and in the presence of its oxidative degradates were developed. These methods are indirect, involve the addition of excess oxidant [N-bromosuccinimide
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